Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Heterocycles with oxygen → 2-furancarboxaldehyde

FORMULA:	C₅H₄O₂
TRIVIAL NAME:	furfural; 2-furanaldehyde
CAS RN:	98-01-1
STRUCTURE (FROM NIST):
InChIKey:	HYBBIBNJHNGZAN-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
2.6		HSDB (2015)	V
2.7		Mackay et al. (2006c)	V
2.7		Mackay et al. (1995)	V
6.0		Hilal et al. (2008)	Q
7.2×10⁻²		Emel’yanenko et al. (2007)	Q	166)
7.2×10⁻²		Hertel and Sommer (2006)	Q	166)
	6100	Kühne et al. (2005)	Q
	5900	Kühne et al. (2005)	?

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Emel’yanenko, V. N., Dabrowska, A., Verevkin, S. P., Hertel, M. O., Scheuren, H., & Sommer, K.: Vapor pressures, enthalpies of vaporization, and limiting activity coefficients in water at 100 ∘C of 2-furanaldehyde, benzaldehyde, phenylethanal, and 2-phenylethanol, J. Chem. Eng. Data, 52, 468–471, doi:10.1021/JE060406C (2007).
Hertel, M. O. & Sommer, K.: Limiting separation factors and limiting activity coefficients for 2-furfural, γ-nonalactone, benzaldehyde, and linalool in water at 100 ∘C, J. Chem. Eng. Data, 51, 1283–1285, doi:10.1021/JE0600404 (2006).
Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), URL http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm (2015).
Kühne, R., Ebert, R.-U., & Schüürmann, G.: Prediction of the temperature dependency of Henry’s law constant from chemical structure, Environ. Sci. Technol., 39, 6705–6711, doi:10.1021/ES050527H (2005).
Mackay, D., Shiu, W. Y., & Ma, K. C.: Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Oxygen, Nitrogen, and Sulfur Containing Compounds, Lewis Publishers, Boca Raton (1995).
Mackay, D., Shiu, W. Y., Ma, K. C., & Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. III of Oxygen Containing Compounds, CRC/Taylor & Francis Group (2006c).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

166)	Value at T = 373 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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