Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Organic species with oxygen (O) → Polyols (R(OH)_n) → 2-methylerythritol

FORMULA:	C₅H₁₂O₄
CAS RN:	93921-83-6
STRUCTURE (FROM NIST):
InChIKey:	HGVJFBSSLICXEM-CRCLSJGQSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
3.1×10⁸		Qin et al. (2021)	M	436)
2.4×10⁴		Qin et al. (2021)	Q	437)
3.3×10⁸		Qin et al. (2021)	Q	438)
6.2×10¹⁰		Isaacman-VanWertz et al. (2016)	Q	440) 441)
3.1×10⁸		Isaacman-VanWertz et al. (2016)	Q	442) 443)
3.1×10⁴		Isaacman-VanWertz et al. (2016)	Q	444)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Isaacman-VanWertz, G., Yee, L. D., Kreisberg, N. M., Wernis, R., Moss, J. A., Hering, S. V., de Sá, S. S., Martin, S. T., Alexander, M. L., Palm, B. B., Hu, W., Campuzano-Jost, P., Day, D. A., Jimenez, J. L., Riva, M., Surratt, J. D., Viegas, J., Manzi, A., Edgerton, E., Baumann, K., Souza, R., Artaxo, P., & Goldstein, A. H.: Ambient gas-particle partitioning of tracers for biogenic oxidation, Environ. Sci. Technol., 50, 9952–9962, doi:10.1021/ACS.EST.6B01674 (2016).
Qin, C., Gou, Y., Wang, Y., Mao, Y., Liao, H., Wang, Q., & Xie, M.: Gas–particle partitioning of polyol tracers at a suburban site in Nanjing, east China: increased partitioning to the particle phase, Atmos. Chem. Phys., 21, 12 141–12 153, doi:10.5194/ACP-21-12141-2021 (2021).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

436)	Calculated based on atmospheric measurements.
437)	Calculated using EPI.
438)	Calculated using SPARC.
440)	Isaacman-VanWertz et al. (2016) refer to Raventos-Duran et al. (2010) as the source, but the quoted value cannot be found there.
441)	Calculated using GROMHE.
442)	Isaacman-VanWertz et al. (2016) refer to a paper by Hilal et al. as the source, but the quoted value cannot be found there.
443)	Calculated using SPARC.
444)	Calculated using the bond contribution of HENRYWIN.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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