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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with chlorine (Cl)Chlorocarbons (C, H, Cl) → trichloroethene

FORMULA:C2HCl3
TRIVIAL NAME: trichloroethylene
CAS RN:79-01-6
STRUCTURE
(FROM NIST):
InChIKey:XSTXAVWGXDQKEL-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.1×10−3 4300 Warneck (2007) L
1.0×10−3 4300 Fogg and Sangster (2003) L
1.0×10−3 4600 Staudinger and Roberts (2001) L
9.9×10−4 4600 Staudinger and Roberts (1996) L
6.6×10−4 Steward et al. (1973) L 19)
1.2×10−3 4700 Hiatt (2013) M
1.3×10−3 Zhang et al. (2013) M
1.0×10−3 3900 Chen et al. (2012) M
9.4×10−4 Helburn et al. (2008) M
1.0×10−3 3900 Shimotori and Arnold (2003) M
1.1×10−3 4200 Görgényi et al. (2002) M
1.2×10−3 3600 Bierwagen and Keller (2001) M
7.6×10−4 4900 Moore (2000) M 127)
1.0×10−3 David et al. (2000) M 126)
1.1×10−3 3900 Vane and Giroux (2000) M
9.5×10−4 4900 Dewulf et al. (1999) M
9.5×10−4 Ryu and Park (1999) M
9.3×10−4 3700 Heron et al. (1998) M
1.1×10−3 Chiang et al. (1998) M 9)
1.4×10−3 Peng and Wan (1998) M
8.7×10−4 4000 Peng and Wan (1998) M 127)
1.1×10−3 3800 Peng and Wan (1997) M
1.3×10−3 Hovorka and Dohnal (1997) M 9)
1.1×10−3 2200 Kondoh and Nakajima (1997) M
8.8×10−4 3600 Park et al. (1997) M
8.5×10−4 Turner et al. (1996) M
8.3×10−4 Ramachandran et al. (1996) M
1.2×10−3 3900 Dewulf et al. (1995) M
1.3×10−3 Nielsen et al. (1994) M
9.7×10−4 4300 Khalfaoui and Newsham (1994b) M
9.5×10−4 3500 Robbins et al. (1993) M
1.1×10−3 Hoff et al. (1993) M
1.0×10−3 Li et al. (1993) M
1.1×10−3 4200 Wright et al. (1992) M
1.1×10−3 4200 Tse et al. (1992) M
9.8×10−4 4100 Cooling et al. (1992) M
1.3×10−3 5200 Tancrède and Yanagisawa (1990) M
1.0×10−3 5200 Bissonette et al. (1990) M
9.7×10−4 2000 Lamarche and Droste (1989) M 135)
5.5×10−4 Guitart et al. (1989) M 19)
9.5×10−4 3700 Ashworth et al. (1988) M 103)
1.0×10−3 4800 Gossett (1987) M
9.6×10−4 4700 Munz and Roberts (1987) M
9.8×10−4 Hellmann (1987) M 31)
9.4×10−4 Yurteri et al. (1987) M 9)
9.0×10−4 5400 Schoene and Steinhanses (1985) M
1.1×10−3 4300 Gossett et al. (1985) M
1.0×10−3 Garbarini and Lion (1985) M
9.7×10−4 4900 Lincoff and Gossett (1984) M
1.0×10−3 4600 Leighton and Calo (1981) M
7.4×10−4 4800 Ervin et al. (1980) M
8.4×10−4 Warner et al. (1980) M
5.0×10−4 Sato and Nakajima (1979b) M 19)
1.1×10−3 Pearson and McConnell (1975) M 9) 248)
8.5×10−4 Mackay et al. (2006b) V
9.9×10−4 Park et al. (1997) V
8.4×10−4 Mackay et al. (1993) V
1.1×10−3 Hwang et al. (1992) V
8.1×10−4 Mackay and Shiu (1981) V
8.4×10−4 Warner et al. (1980) V
8.2×10−4 Dilling (1977) V 249)
1.0×10−3 Dilling (1977) V 9)
2.4×10−3 Dilling (1977) V 66)
8.4×10−4 Hine and Mookerjee (1975) V
8.4×10−4 Dilling et al. (1975) V
8.8×10−4 1600 Goldstein (1982) X 116)
1.1×10−3 Ryan et al. (1988) C
8.4×10−4 Shen (1982) C
3.0×10−4 Hilal et al. (2008) Q
3600 Kühne et al. (2005) Q
8.4×10−3 Nirmalakhandan and Speece (1988a) Q
9.7×10−4 Mackay et al. (2006b) ?
4200 Kühne et al. (2005) ?
9.7×10−4 Mackay et al. (1993) ?
8.4×10−4 Yaws and Yang (1992) ? 92)
8.4×10−4 Abraham et al. (1990) ?

References

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Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
19) Value at T = 310 K.
31) Value at T = 295 K.
66) Value at T = 275 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
103) The value is most probably taken from the report by Howe et al. (1987).
116) Value given here as quoted by Staudinger and Roberts (1996).
126) Value at T = 296 K.
127) Solubility in sea water.
135) The temperature dependence is recalculated using the data in Table 4 of Lamarche and Droste (1989) and not taken from their Table 5.
248) The same data were also published in McConnell et al. (1975).
249) Values at different temperatures are from different sources. Thus a temperature dependence was not calculated.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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