When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
A new version is currently under peer review:
R. Sander: Compilation of Henry's law constants (version 5.0.0-rc.0)
for water as solvent,
doi:10.5194/egusphere-2023-1584
The database on this web page will be updated to
version 5.0.0 when the peer review of the manuscript is completed.
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|
|
References |
Type |
Notes |
| [mol/(m3Pa)] |
[K] |
|
|
|
| 6.5 |
5900 |
Sander et al. (2011) |
L |
|
| 6.5 |
5900 |
Sander et al. (2006) |
L |
|
| 6.5 |
5900 |
Huthwelker et al. (1995) |
L |
|
| 9.1 |
|
Blatchley et al. (1992) |
M |
9)
|
| 4.7 |
1600 |
Hanson and Ravishankara (1991) |
M |
55)
|
| 6.0 |
4900 |
Holzwarth et al. (1984) |
M |
56)
|
| 2.6 |
5100 |
Wagman et al. (1982) |
T |
|
| 5.4 |
|
Hilal et al. (2008) |
Q |
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Blatchley, III, E. R., Johnson, R. W., Alleman, J. E., & McCoy, W. F.: Effective Henry’s law constants for free chlorine and free bromine, Wat. Res., 26, 99–106, doi:10.1016/0043-1354(92)90117-M (1992).
-
Hanson, D. R. & Ravishankara, A. R.: The reaction probabilities of ClONO2 and N2O5 on 40 to 75% sulfuric acid solutions, J. Geophys. Res., 96D, 17 307–17 314, doi:10.1029/91JD01750 (1991).
-
Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
-
Holzwarth, G., Balmer, R. G., & Soni, L.: The fate of chlorine and chloramines in cooling towers, Wat. Res., 18, 1421–1427, doi:10.1016/0043-1354(84)90012-5 (1984).
-
Huthwelker, T., Clegg, S. L., Peter, T., Carslaw, K., Luo, B. P., & Brimblecombe, P.: Solubility of HOCl in water and aqueous H2SO4 to stratospheric temperatures, J. Atmos. Chem., 21, 81–95, doi:10.1007/BF00712439 (1995).
-
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL http://jpldataeval.jpl.nasa.gov (2006).
-
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL http://jpldataeval.jpl.nasa.gov (2011).
-
Wagman, D. D., Evans, W. H., Parker, V. B., Schumm, R. H., Halow, I., Bailey, S. M., Churney, K. L., & Nuttall, R. L.: The NBS tables of chemical thermodynamic properties; Selected values for inorganic and C1 and C2 organic substances in SI units, J. Phys. Chem. Ref. Data, 11, suppl. 2 (1982).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
| 9) |
Value at T = 293 K. |
| 55) |
This value was extrapolated from data at T = 215 K and T = 263 K. |
| 56) |
Value at pH = 6.5. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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