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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.


Henry's Law ConstantsInorganic speciesFluorine (F) → nitrogen trifluoride

FORMULA:NF3
CAS RN:7783-54-2
STRUCTURE
(FROM NIST):
InChIKey:GVGCUCJTUSOZKP-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) References Type Notes
[mol/(m3Pa)] [K]
7.9×10−6 1900 Burkholder et al. (2019) L 1)
7.9×10−6 1900 Burkholder et al. (2015) L 1)
7.9×10−6 1900 Sander et al. (2011) L 1)
7.9×10−6 1900 Wilhelm et al. (1977) L
7.7×10−6 1700 Dean et al. (1973) M 108)
7.8×10−6 1900 Ashton et al. (1968) M 109)

Data

The first column contains Henry's law solubility constant Hscp at the reference temperature of 298.15 K.
The second column contains the temperature dependence d ln Hs cp / d (1/T), also at the reference temperature.

References

  • Ashton, J. T., Dawe, R. A., Miller, K. W., Smith, E. B., & Stickings, B. J.: The solubility of certain gaseous fluorine compounds in water, J. Chem. Soc. A, pp. 1793–1796, doi:10.1039/J19680001793 (1968).
  • Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18, JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2015).
  • Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C., Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Percival, C. J., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2019).
  • Dean, C. R. S., Finch, A., & Gardner, P. J.: The aqueous solubilities of nitrogen trifluoride and dinitrogen tetrafluoride, J. Chem. Soc. Dalton Trans., pp. 2722–2725, doi:10.1039/DT9730002722 (1973).
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2011).
  • Wilhelm, E., Battino, R., & Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219–262, doi:10.1021/CR60306A003 (1977).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

1) A detailed temperature dependence with more than one parameter is available in the original publication. Here, only the temperature dependence at 298.15 K according to the van 't Hoff equation is presented.
108) The data from Dean et al. (1973) were fitted to the three-parameter equation: Hscp= exp( −164.52717 +8214.77776/T +21.97482 ln(T)) mol m−3 Pa−1, with T in K.
109) The data from Ashton et al. (1968) were fitted to the three-parameter equation: Hscp= exp( −279.21972 +13536.60588/T +38.97386 ln(T)) mol m−3 Pa−1, with T in K.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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