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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesSulfur (S) → hydrogen sulfide

FORMULA:H2S
CAS RN:7783-06-4
STRUCTURE
(FROM NIST):
InChIKey:RWSOTUBLDIXVET-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.0×10−3 2100 Sander et al. (2011) L
1.0×10−3 2100 Sander et al. (2006) L
1.0×10−3 2000 Fernández-Prini et al. (2003) L 1)
1.0×10−3 2200 Carroll and Mather (1989) L
1.0×10−3 2000 Yoo et al. (1986) L
1.0×10−3 2100 Edwards et al. (1978) L
1.0×10−3 2100 Wilhelm et al. (1977) L
9.1×10−4 1700 Rinker and Sandall (2000) M
8.6×10−4 2100 De Bruyn et al. (1995b) M
1.1×10−3 2300 Suleimenov and Krupp (1994) M
9.4×10−4 2300 Barrett et al. (1988) M
1.0×10−3 2100 Winkler (1906) M
9.6×10−4 2000 Iliuta and Larachi (2007) R
1.0×10−3 Hine and Weimar (1965) R
1.0×10−3 1900 Fogg and Young (1988) X 5)
1.0×10−3 2300 Dean (1992) ? 6)
Chapoy et al. (2005) W 74)

References

  • Barrett, T. J., Anderson, G. M., & Lugowski, J.: The solubility of hydrogen sulphide in 0-5 m NaCl solutions at 25 -95 C and one atmosphere, Geochim. Cosmochim. Acta, 52, 807–811, doi:10.1016/0016-7037(88)90352-3 (1988).
  • Carroll, J. J. & Mather, A. E.: The solubility of hydrogen sulphide in water from 0 to 90 C and pressures to 1 MPa, Geochim. Cosmochim. Acta, 53, 1163–1170, doi:10.1016/0016-7037(89)90053-7 (1989).
  • Chapoy, A., Mohammadi, A. H., Tohidi, B., Valtz, A., & Richon, D.: Experimental measurement and phase behavior modeling of hydrogen sulfide-water binary system, Ind. Eng. Chem. Res., 44, 7567–7574, doi:10.1021/IE050201H (2005).
  • Dean, J. A.: Lange’s Handbook of Chemistry, McGraw-Hill, Inc. (1992).
  • De Bruyn, W. J., Swartz, E., Hu, J. H., Shorter, J. A., Davidovits, P., Worsnop, D. R., Zahniser, M. S., & Kolb, C. E.: Henry’s law solubilities and Śetchenow coefficients for biogenic reduced sulfur species obtained from gas-liquid uptake measurements, J. Geophys. Res., 100D, 7245–7251, doi:10.1029/95JD00217 (1995b).
  • Edwards, T. J., Maurer, G., Newman, J., & Prausnitz, J. M.: Vapor-liquid equilibria in multicomponent aqueous solutions of volatile weak electrolytes, AIChE J., 24, 966–976, doi:10.1002/AIC.690240605 (1978).
  • Fernández-Prini, R., Alvarez, J. L., & Harvey, A. H.: Henry’s constants and vapor-liquid distribution constants for gaseous solutes in H2O and D2O at high temperatures, J. Phys. Chem. Ref. Data, 32, 903–916, doi:10.1063/1.1564818 (2003).
  • Fogg, P. G. T. & Young, C. L., eds.: IUPAC Solubility Data Series, vol. 32 of Hydrogen Sulfide, Deuterium Sulfide, and Hydrogen Selenide, Pergamon Press, Oxford, England (1988).
  • Hine, J. & Weimar, Jr., R. D.: Carbon basicity, J. Am. Chem. Soc., 87, 3387–3396, doi:10.1021/JA01093A018 (1965).
  • Iliuta, M. C. & Larachi, F.: Solubility of total reduced sulfurs (hydrogen sulfide, methyl mercaptan, dimethyl sulfide, and dimethyl disulfide) in liquids, J. Chem. Eng. Data, 52, 2–19, doi:10.1021/JE060263U (2007).
  • Rinker, E. B. & Sandall, O. C.: Physical solubility of hydrogen sulfide in several aqueous solvents, Can. J. Chem. Eng., 78, 232–236, doi:10.1002/CJCE.5450780130 (2000).
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL http://jpldataeval.jpl.nasa.gov (2006).
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL http://jpldataeval.jpl.nasa.gov (2011).
  • Suleimenov, O. M. & Krupp, R. E.: Solubility of hydrogen sulfide in pure water and in NaCl solutions, from 20 to 320 C and at saturation pressures, Geochim. Cosmochim. Acta, 58, 2433–2444, doi:10.1016/0016-7037(94)90022-1 (1994).
  • Wilhelm, E., Battino, R., & Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219–262, doi:10.1021/CR60306A003 (1977).
  • Winkler, L. W.: Gesetzmässigkeit bei der Absorption der Gase in Flüssigkeiten, Z. Phys. Chem., 55, 344–354, doi:10.1515/ZPCH-1906-5518 (1906).
  • Yoo, K.-P., Lee, S. Y., & Lee, W. H.: Ionization and Henry’s law constants for volatile, weak electrolyte water pollutants, Korean J. Chem. Eng., 3, 67–72, doi:10.1007/BF02697525 (1986).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

1) Vapor pressure data for water from Wagner and Pruss (1993) was needed to calculate Hs.
5) Value given here as quoted by Lide and Frederikse (1995).
6) Only the tabulated data between T = 273 K and T = 303 K from Dean (1992) were used to derive Hs and its temperature dependence. Above T = 303 K, the tabulated data could not be parameterized very well. The partial pressure of water vapor (needed to convert some Henry's law constants) was calculated using the formula given by Sander et al. (1995). The quantities A and α from Dean (1992) were assumed to be identical.
74) The parameter fit for the temperature dependence is incorrect. A corrected version was later presented by Iliuta and Larachi (2007).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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