Henry's Law Constants

https://www.henrys-law.org, https://henry.mpch-mainz.gwdg.de

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Inorganic species → Hydrogen (H) → hydrogen peroxide

FORMULA:	H₂O₂
CAS RN:	7722-84-1
STRUCTURE (FROM NIST):
InChIKey:	MHAJPDPJQMAIIY-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
8.6×10²	7300	Burkholder et al. (2019)	L
8.6×10²	7300	Burkholder et al. (2015)	L
9.5×10²	7200	Brockbank (2013)	L
9.1×10²	6600	Warneck & Williams (2012)	L
8.3×10²	7600	Sander et al. (2011)	L
7.6×10²	7300	Sander et al. (2006)	L
9.8×10²	6100	Fogg & Sangster (2003)	L	52)
1.2×10³	5900	Rivera-Rios (2018)	M
1.1×10³	7000	Huang & Chen (2010)	M
8.2×10²	7400	O’Sullivan et al. (1996)	M
9.9×10²	6300	Lind & Kok (1994)	M	53)
		Staffelbach & Kok (1993)	M	54)
8.5×10²	6500	Zhou & Lee (1992)	M
6.7×10²	7900	Hwang & Dasgupta (1985)	M
1.4×10³		Yoshizumi et al. (1984)	M	12)
9.6×10²	6600	Chameides (1984)	T
7.0×10²	7000	Martin & Damschen (1981)	T
6.4×10¹		Hilal et al. (2008)	Q
7.0×10²	7300	Seinfeld (1986)	?	21)
7.0×10²	7300	Hoffmann & Jacob (1984)	?	21)
		Pandis & Seinfeld (1989)	W	55)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Brockbank, S. A.: Aqueous Henry’s law constants, infinite dilution activity coefficients, and water solubility: critically evaluated database, experimental analysis, and prediction methods, Ph.D. thesis, Brigham Young University, USA, URL https://scholarsarchive.byu.edu/etd/3691/ (2013).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18, JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2015).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C., Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Percival, C. J., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2019).
Chameides, W. L.: The photochemistry of a remote marine stratiform cloud, J. Geophys. Res., 89, 4739–4755, doi:10.1029/JD089ID03P04739 (1984).
Fogg, P. & Sangster, J.: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, John Wiley & Sons, Inc., ISBN 978-0-471-98651-5 (2003).
Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
Hoffmann, M. R. & Jacob, D. J.: Kinetics and mechanisms of the catalytic oxidation of dissolved sulfur dioxide in aqueous solution: An application to nighttime fog water chemistry, in: SO₂, NO and NO₂ Oxidation Mechanisms: Atmospheric Considerations, edited by Calvert, J. G., pp. 101–172, Butterworth Publishers, Boston, MA, ISBN 0250405687 (1984).
Huang, D. & Chen, Z.: Reinvestigation of the Henry’s law constant for hydrogen peroxide with temperature and acidity variation, J. Environ. Sci., 22, 570–574, doi:10.1016/S1001-0742(09)60147-9 (2010).
Hwang, H. & Dasgupta, P. G.: Thermodynamics of the hydrogen peroxide-water system, Environ. Sci. Technol., 19, 255–258, doi:10.1021/ES00133A006 (1985).
Lind, J. A. & Kok, G. L.: Correction to “Henry’s law determinations for aqueous solutions of hydrogen peroxide, methylhydroperoxide, and peroxyacetic acid” by John A. Lind and Gregory L. Kok, J. Geophys. Res., 99, 21 119, doi:10.1029/94JD01155 (1994).
Martin, L. R. & Damschen, D. E.: Aqueous oxidation of sulfur dioxide by hydrogen peroxide at low pH, Atmos. Environ., 15, 1615–1621, doi:10.1016/0004-6981(81)90146-3 (1981).
O’Sullivan, D. W., Lee, M., Noone, B. C., & Heikes, B. G.: Henry’s law constant determinations for hydrogen peroxide, methyl hydroperoxide, hydroxymethyl hydroperoxide, ethyl hydroperoxide, and peroxyacetic acid, J. Phys. Chem., 100, 3241–3247, doi:10.1021/JP951168N (1996).
Pandis, S. N. & Seinfeld, J. H.: Sensitivity analysis of a chemical mechanism for aqueous-phase atmospheric chemistry, J. Geophys. Res., 94, 1105–1126, doi:10.1029/JD094ID01P01105 (1989).
Rivera-Rios, J. C.: Atmospheric chemistry of isoprene hydroxyhydroperoxides, Ph.D. thesis, Graduate School of Arts & Sciences, Harvard University, USA, URL https://dash.harvard.edu/handle/1/41127811 (2018).
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL https://jpldataeval.jpl.nasa.gov (2006).
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2011).
Seinfeld, J. H.: Atmospheric Chemistry and Physics of Air Pollution, Wiley-Interscience Publication, NY, ISBN 0471828572 (1986).
Staffelbach, T. A. & Kok, G. L.: Henry’s law constants for aqueous solutions of hydrogen peroxide and hydroxymethyl hydroperoxide, J. Geophys. Res., 98, 12 713–12 717, doi:10.1029/93JD01022 (1993).
Warneck, P. & Williams, J.: The Atmospheric Chemist’s Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0 (2012).
Yoshizumi, K., Aoki, K., Nouchi, I., Okita, T., Kobayashi, T., Kamakura, S., & Tajima, M.: Measurements of the concentration in rainwater and of the Henry’s law constant of hydrogen peroxide, Atmos. Environ., 18, 395–401, doi:10.1016/0004-6981(84)90114-8 (1984).
Zhou, X. & Lee, Y.-N.: Aqueous solubility and reaction kinetics of hydroxymethyl hydroperoxide, J. Phys. Chem., 96, 265–272, doi:10.1021/J100180A051 (1992).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

12)	Value at T = 293 K.
21)	Several references are given in the list of Henry's law constants but not assigned to specific species.
52)	Erratum for page 264 of Fogg & Sangster (2003): the second value from their Ref. [10] refers to 291.15 K, not 281.15 K.
53)	This value is a correction of the solubility published by Lind & Kok (1986).
54)	This value was measured at low pH. It is superseded by a later publication of the same group (Lind & Kok, 1994).
55)	Pandis & Seinfeld (1989) cite an incorrect value from Lind & Kok (1986); see erratum by Lind & Kok (1994).

References cited in the notes can be found here.

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https://www.henrys-law.org, https://henry.mpch-mainz.gwdg.de

Rolf Sander

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