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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsInorganic speciesNitrogen (N) → ammonia

FORMULA:NH3
CAS RN:7664-41-7
STRUCTURE
(FROM NIST):
InChIKey:QGZKDVFQNNGYKY-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
5.9×10−1 4200 Sander et al. (2011) L
5.9×10−1 4200 Sander et al. (2006) L
5.8×10−1 4400 Yoo et al. (1986) L
6.0×10−1 4200 Edwards et al. (1978) L
1.0×10−1 1500 Wilhelm et al. (1977) L
2.8×10−1 3200 Shi et al. (1999) M
6.0×10−1 4200 Clegg and Brimblecombe (1989) M
5.5×10−1 4100 Dasgupta and Dong (1986) M
7.7×10−1 Holzwarth et al. (1984) M
7.4×10−1 3700 Hales and Drewes (1979) M
5.6×10−1 4200 Dasgupta and Dong (1986) T
5.7×10−1 4100 Chameides (1984) T
6.1×10−1 Van Krevelen et al. (1949) X 20)
2.7×10−1 2100 Dean (1992) ? 6)
5.7×10−1 Abraham et al. (1990) ?
6.1×10−1 4100 Seinfeld (1986) ? 7)
5.8×10−1 4100 Hoffmann and Jacob (1984) ? 7)
5.2×10−1 Bone et al. (1983) ? 21)

References

  • Abraham, M. H., Whiting, G. S., Fuchs, R., & Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291–300, doi:10.1039/P29900000291 (1990).
  • Bone, R., Cullis, P., & Wolfenden, R.: Solvent effects on equilibria of addition of nucleophiles to acetaldehyde and the hydrophilic character of diols, J. Am. Chem. Soc., 105, 1339–1343, doi:10.1021/JA00343A044 (1983).
  • Chameides, W. L.: The photochemistry of a remote marine stratiform cloud, J. Geophys. Res., 89D, 4739–4755, doi:10.1029/JD089ID03P04739 (1984).
  • Clegg, S. L. & Brimblecombe, P.: Solubility of ammonia in pure aqueous and multicomponent solutions, J. Phys. Chem., 93, 7237–7248, doi:10.1021/J100357A041 (1989).
  • Dasgupta, P. G. & Dong, S.: Solubility of ammonia in liquid water and generation of trace levels of standard gaseous ammonia, Atmos. Environ., 20, 565–570, doi:10.1016/0004-6981(86)90099-5 (1986).
  • Dean, J. A.: Lange’s Handbook of Chemistry, McGraw-Hill, Inc. (1992).
  • Edwards, T. J., Maurer, G., Newman, J., & Prausnitz, J. M.: Vapor-liquid equilibria in multicomponent aqueous solutions of volatile weak electrolytes, AIChE J., 24, 966–976, doi:10.1002/AIC.690240605 (1978).
  • Hales, J. M. & Drewes, D. R.: Solubility of ammonia in water at low concentrations, Atmos. Environ., 13, 1133–1147, doi:10.1016/0004-6981(79)90037-4 (1979).
  • Hoffmann, M. R. & Jacob, D. J.: Kinetics and mechanisms of the catalytic oxidation of dissolved sulfur dioxide in aqueous solution: An application to nighttime fog water chemistry, in: SO2, NO and NO2 Oxidation Mechanisms: Atmospheric Considerations, edited by Calvert, J. G., pp. 101–172, Butterworth Publishers, Boston, MA (1984).
  • Holzwarth, G., Balmer, R. G., & Soni, L.: The fate of chlorine and chloramines in cooling towers, Wat. Res., 18, 1421–1427, doi:10.1016/0043-1354(84)90012-5 (1984).
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL http://jpldataeval.jpl.nasa.gov (2006).
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL http://jpldataeval.jpl.nasa.gov (2011).
  • Seinfeld, J. H.: Atmospheric Chemistry and Physics of Air Pollution, Wiley-Interscience Publication, NY (1986).
  • Shi, Q., Davidovits, P., Jayne, J. T., Worsnop, D. R., & Kolb, C. E.: Uptake of gas-phase ammonia. 1. Uptake by aqueous surfaces as a function of pH, J. Phys. Chem. A, 103, 8812–8823, doi:10.1021/JP991696P (1999).
  • Van Krevelen, D. W., Hoftijzer, P. J., & Huntjens, F. J.: Composition and vapor pressures of aqueous solutions of ammonia, carbon dioxide and hydrogen sulfide, Recl. Trav. Chim. Pays-Bas, 68, 191–216 (1949).
  • Wilhelm, E., Battino, R., & Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219–262, doi:10.1021/CR60306A003 (1977).
  • Yoo, K.-P., Lee, S. Y., & Lee, W. H.: Ionization and Henry’s law constants for volatile, weak electrolyte water pollutants, Korean J. Chem. Eng., 3, 67–72, doi:10.1007/BF02697525 (1986).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

6) Only the tabulated data between T = 273 K and T = 303 K from Dean (1992) were used to derive Hs and its temperature dependence. Above T = 303 K, the tabulated data could not be parameterized very well. The partial pressure of water vapor (needed to convert some Henry's law constants) was calculated using the formula given by Sander et al. (1995). The quantities A and α from Dean (1992) were assumed to be identical.
7) Several references are given in the list of Henry's law constants but not assigned to specific species.
20) Value given here as quoted by Betterton (1992).
21) Bone et al. (1983) gives Carter et al. (1968) as the source. However, no data were found in that reference.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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