Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Organic species with oxygen (O) → Ethers (ROR) → propyl vinyl ether

FORMULA:	C₅H₁₀O
CAS RN:	764-47-6
STRUCTURE (FROM NIST):
InChIKey:	OVGRCEFMXPHEBL-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
3.1×10⁻³	4800	Hwang et al. (2010)	M	11) 521)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Hwang, I.-C., Kwak, H.-Y., & Park, S.-J.: Determination and prediction of K_ow and dimensionless Henry’s constant (H) for 6 ether compounds at several temperatures, J. Ind. Eng. Chem., 16, 629–633, doi:10.1016/J.JIEC.2010.03.003 (2010).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

11)	Measured at high temperature and extrapolated to T^⊖ = 298.15 K.
521)	Hwang et al. (2010) present regression parameters in their Table 6 and values extrapolated to 298.15 K in their Table 5. However, I was not able to reproduce their calculation. The data shown here are from my own regression of the measured data between 318.15 K and 333.15 K.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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