MPG

Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


Home

Henry's Law Constants

Notes

References

Download

Errata

Contact, Impressum, Acknowledgements


When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with chlorine (Cl)Chlorocarbons (C, H, Cl) → dichloromethane

FORMULA:CH2Cl2
TRIVIAL NAME: methylene chloride
CAS RN:75-09-2
STRUCTURE
(FROM NIST):
InChIKey:YMWUJEATGCHHMB-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
3.6×10−3 4100 Sander et al. (2011) L
3.9×10−3 3700 Warneck (2007) L
3.6×10−3 4100 Sander et al. (2006) L
3.6×10−3 4100 Staudinger and Roberts (2001) L
3.6×10−3 4100 Staudinger and Roberts (1996) L
3.8×10−3 Mackay and Shiu (1981) L
4.0×10−3 3900 Hiatt (2013) M
3.5×10−3 2300 Chen et al. (2012) M
3.2×10−3 Helburn et al. (2008) M
3.3×10−3 4200 Moore (2000) M 127)
3.9×10−3 David et al. (2000) M 126)
4.1×10−3 Ryu and Park (1999) M
3.4×10−3 Chiang et al. (1998) M 9) 250)
5.1×10−3 Hovorka and Dohnal (1997) M 9)
3.7×10−3 3200 Kondoh and Nakajima (1997) M
4.3×10−3 3500 Park et al. (1997) M
4.1×10−3 Hoff et al. (1993) M
3.8×10−3 Li et al. (1993) M
3.9×10−3 3800 Wright et al. (1992) M
3.9×10−3 3500 Tse et al. (1992) M
3.4×10−3 Guitart et al. (1989) M 19)
3.4×10−3 4300 Ashworth et al. (1988) M 103)
4.6×10−3 3800 Gossett (1987) M
5.7×10−3 Hellmann (1987) M 31)
5.2×10−3 Yurteri et al. (1987) M 9)
3.8×10−3 4500 Gossett et al. (1985) M
3.4×10−3 4200 Lincoff and Gossett (1984) M
3.0×10−3 3600 Leighton and Calo (1981) M
3.1×10−3 Warner et al. (1980) M
2.8×10−3 Sato and Nakajima (1979b) M 19)
3.3×10−3 Pearson and McConnell (1975) M 9) 248)
4.2×10−3 4400 Hartkopf and Karger (1973) M
4.1×10−3 4000 Rex (1906) M
2.7×10−3 Mackay et al. (2006b) V
3.5×10−3 4100 Fogg and Sangster (2003) V
4.0×10−3 Park et al. (1997) V
5.9×10−3 Mackay et al. (1993) V
2.9×10−3 Hwang et al. (1992) V
3.2×10−3 Warner et al. (1980) V
4.0×10−3 Dilling (1977) V 249)
1.2×10−2 Dilling (1977) V 66)
4.3×10−3 Hine and Mookerjee (1975) V
4.0×10−3 Dilling et al. (1975) V
3.1×10−3 3600 Goldstein (1982) X 116)
4.2×10−3 Harrison et al. (1993) C
3.4×10−3 Harrison et al. (1993) C
4.7×10−3 Ryan et al. (1988) C
3.1×10−3 Shen (1982) C
3.7×10−3 Dilling (1977) C
3.7×10−3 Dilling et al. (1975) C
9.0×10−3 Hilal et al. (2008) Q
3000 Kühne et al. (2005) Q
2.2×10−3 Nirmalakhandan and Speece (1988a) Q
3.3×10−3 Mackay et al. (2006b) ?
3900 Kühne et al. (2005) ?
4.0×10−3 Yaws (1999) ?
3.3×10−3 Mackay et al. (1993) ?
4.0×10−3 Yaws and Yang (1992) ? 92)
3.7×10−3 Abraham et al. (1990) ?

References

  • Abraham, M. H., Whiting, G. S., Fuchs, R., & Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291–300, doi:10.1039/P29900000291 (1990).
  • Ashworth, R. A., Howe, G. B., Mullins, M. E., & Rogers, T. N.: Air-water partitioning coefficients of organics in dilute aqueous solutions, J. Hazard. Mater., 18, 25–36, doi:10.1016/0304-3894(88)85057-X (1988).
  • Chen, F., Freedman, D. L., Falta, R. W., & Murdoch, L. C.: Henry’s law constants of chlorinated solvents at elevated temperatures, Chemosphere, 86, 156–165, doi:10.1016/J.CHEMOSPHERE.2011.10.004 (2012).
  • Chiang, P.-C., Hung, C.-H., Mar, J. C., & Chang, E. E.: Henry’s constants and mass transfer coefficients of halogenated organic pollutants in an air stripping packed column, Wat. Sci. Tech., 38, 287–294 (1998).
  • David, M. D., Fendinger, N. J., & Hand, V. C.: Determination of Henry’s law constants for organosilicones in actual and simulated wastewater, Environ. Sci. Technol., 34, 4554–4559, doi:10.1021/ES991204M (2000).
  • Dilling, W. L.: Interphase transfer processes. II. Evaporation rates of chloro methanes, ethanes, ethylenes, propanes, and propylenes from dilute aqueous solutions. Comparisons with theoretical predictions, Environ. Sci. Technol., 11, 405–409, doi:10.1021/ES60127A009 (1977).
  • Dilling, W. L., Tefertiller, N. B., & Kallos, G. J.: Evaporation rates and reactivities of methylene chloride, chloroform, 1,1,1-trichloroethane, trichloroethylene, tetrachloroethylene, and other chlorinated compounds in dilute aqueous solutions, Environ. Sci. Technol., 9, 833–838, doi:10.1021/ES60107A008 (1975).
  • Fogg, P. & Sangster, J.: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, John Wiley & Sons, Inc. (2003).
  • Goldstein, D. J.: Air and steam stripping of toxic pollutants, Appendix 3: Henry’s law constants, Tech. Rep. EPA-68-03-002, Industrial Environmental Research Laboratory, Cincinnati, OH, USA (1982).
  • Gossett, J. M.: Measurement of Henry’s law constants for C1 and C2 chlorinated hydrocarbons, Environ. Sci. Technol., 21, 202–208, doi:10.1021/ES00156A012 (1987).
  • Gossett, J. M., Cameron, C. E., Eckstrom, B. P., Goodman, C., & Lincoff, A. H.: Mass transfer coefficients and Henry’s constants for packed-tower air stripping of volatile organics: Measurements and Correlations, Final Report ESL-TR-85-18, Engineering and Services Laboratory, Tyndall Air Force Base, FL (1985).
  • Guitart, R., Puigdemont, F., & Arboix, M.: Rapid headspace gas chromatographic method for the determination of liquid/gas partition coefficients, J. Chromatogr., 491, 271–280, doi:10.1016/S0378-4347(00)82845-5 (1989).
  • Harrison, D. P., Valsaraj, K. T., & Wetzel, D. M.: Air stripping of organics from ground water, Waste Manage., 13, 417–429, doi:10.1016/0956-053X(93)90074-7 (1993).
  • Hartkopf, A. & Karger, B. L.: Study of the interfacial properties of water by gas chromatography, Acc. Chem. Res., 6, 209–216, doi:10.1021/AR50066A006 (1973).
  • Helburn, R., Albritton, J., Howe, G., Michael, L., & Franke, D.: Henry’s law constants for fragrance and organic solvent compounds in aqueous industrial surfactants, J. Chem. Eng. Data, 53, 1071–1079, doi:10.1021/JE700418A (2008).
  • Hellmann, H.: Model tests on volatilization of organic trace substances in surfaces waters, Fresenius J. Anal. Chem., 328, 475–479, doi:10.1007/BF00475967 (1987).
  • Hiatt, M. H.: Determination of Henry’s law constants using internal standards with benchmark values, J. Chem. Eng. Data, 58, 902–908, doi:10.1021/JE3010535 (2013).
  • Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
  • Hine, J. & Mookerjee, P. K.: The intrinsic hydrophilic character of organic compounds. Correlations in terms of structural contributions, J. Org. Chem., 40, 292–298, doi:10.1021/JO00891A006 (1975).
  • Hoff, J. T., Mackay, D., Gillham, R., & Shiu, W. Y.: Partitioning of organic chemicals at the air-water interface in environmental systems, Environ. Sci. Technol., 27, 2174–2180, doi:10.1021/ES00047A026 (1993).
  • Hovorka, Š. & Dohnal, V.: Determination of air-water partitioning of volatile halogenated hydrocarbons by the inert gas stripping method, J. Chem. Eng. Data, 42, 924–933, doi:10.1021/JE970046G (1997).
  • Hwang, Y.-L., Olson, J. D., & Keller, II, G. E.: Steam stripping for removal of organic pollutants from water. 2. Vapor-liquid equilibrium data, Ind. Eng. Chem. Res., 31, 1759–1768, doi:10.1021/IE00007A022 (1992).
  • Kondoh, H. & Nakajima, T.: Optimization of headspace cryofocus gas chromatography/mass spectrometry for the analysis of 54 volatile organic compounds, and the measurement of their Henry’s constants, J. Environ. Chem., 7, 81–89, doi:10.5985/JEC.7.81 (1997).
  • Kühne, R., Ebert, R.-U., & Schüürmann, G.: Prediction of the temperature dependency of Henry’s law constant from chemical structure, Environ. Sci. Technol., 39, 6705–6711, doi:10.1021/ES050527H (2005).
  • Leighton, D. T. & Calo, J. M.: Distribution coefficients of chlorinated hydrocarbons in dilute air-water systems for groundwater contamination applications, J. Chem. Eng. Data, 26, 382–385, doi:10.1021/JE00026A010 (1981).
  • Li, J., Dallas, A. J., Eikens, D. I., Carr, P. W., Bergmann, D. L., Hait, M. J., & Eckert, C. A.: Measurement of large infinite dilution activity coefficients of nonelectrolytes in water by inert gas stripping and gas chromatography, Anal. Chem., 65, 3212–3218, doi:10.1021/AC00070A008 (1993).
  • Lincoff, A. H. & Gossett, J. M.: The determination of Henry’s law constant for volatile organics by equilibrium partitioning in closed systems, in: Gas transfer at water surfaces, edited by Brutsaert, W. & Jirka, G. H., pp. 17–25, D. Reidel Publishing Company, Dordrecht-Holland, doi:10.1007/978-94-017-1660-4_2 (1984).
  • Mackay, D. & Shiu, W. Y.: A critical review of Henry’s law constants for chemicals of environmental interest, J. Phys. Chem. Ref. Data, 10, 1175–1199, doi:10.1063/1.555654 (1981).
  • Mackay, D., Shiu, W. Y., & Ma, K. C.: Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. III of Volatile Organic Chemicals, Lewis Publishers, Boca Raton (1993).
  • Mackay, D., Shiu, W. Y., Ma, K. C., & Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. II of Halogenated Hydrocarbons, CRC/Taylor & Francis Group (2006b).
  • Moore, R. M.: The solubility of a suite of low molecular weight organochlorine compounds in seawater and implications for estimating the marine source of methyl chloride to the atmosphere, Chemosphere; Global Change Sci., 2, 95–99, doi:10.1016/S1465-9972(99)00045-8 (2000).
  • Nirmalakhandan, N. N. & Speece, R. E.: QSAR model for predicting Henry’s constant, Environ. Sci. Technol., 22, 1349–1357, doi:10.1021/ES00176A016 (1988a).
  • Park, S.-J., Han, S.-D., & Ryu, S.-A.: Measurement of air/water partition coefficient (Henry’s law constant) by using EPICS method and their relationship with vapor pressure and water solubility, J. Korean Inst. Chem. Eng., 35, 915–920 (1997).
  • Pearson, C. R. & McConnell, G.: Chlorinated C1 and C2 hydrocarbons in the marine environment, Proc. R. Soc. Lond. B, 189, 305–332, doi:10.1098/RSPB.1975.0059 (1975).
  • Rex, A.: Über die Löslichkeit der Halogenderivate der Kohlenwasserstoffe in Wasser, Z. Phys. Chem., 55, 355–370, doi:10.1515/ZPCH-1906-5519 (1906).
  • Ryan, J. A., Bell, R. M., Davidson, J. M., & O’Connor, G. A.: Plant uptake of non-ionic organic chemicals from soils, Chemosphere, 17, 2299–2323, doi:10.1016/0045-6535(88)90142-7 (1988).
  • Ryu, S.-A. & Park, S.-J.: A rapid determination method of the air/water partition coefficient and its application, Fluid Phase Equilib., 161, 295–304, doi:10.1016/S0378-3812(99)00193-4 (1999).
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL http://jpldataeval.jpl.nasa.gov (2006).
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL http://jpldataeval.jpl.nasa.gov (2011).
  • Sato, A. & Nakajima, T.: A structure-activity relationship of some chlorinated hydrocarbons, Arch. Environ. Health, 34, 69–75, doi:10.1080/00039896.1979.10667371 (1979b).
  • Shen, T. T.: Estimation of organic compound emissions from waste lagoons, J. Air Pollut. Control Assoc., 32, 79–82, doi:10.1080/00022470.1982.10465374 (1982).
  • Staudinger, J. & Roberts, P. V.: A critical review of Henry’s law constants for environmental applications, Crit. Rev. Environ. Sci. Technol., 26, 205–297, doi:10.1080/10643389609388492 (1996).
  • Staudinger, J. & Roberts, P. V.: A critical compilation of Henry’s law constant temperature dependence relations for organic compounds in dilute aqueous solutions, Chemosphere, 44, 561–576, doi:10.1016/S0045-6535(00)00505-1 (2001).
  • Tse, G., Orbey, H., & Sandler, S. I.: Infinite dilution activity coefficients and Henry’s law coefficients of some priority water pollutants determined by a relative gas chromatographic method, Environ. Sci. Technol., 26, 2017–2022, doi:10.1021/ES00034A021 (1992).
  • Warneck, P.: A review of Henry’s law coefficients for chlorine-containing C1 and C2 hydrocarbons, Chemosphere, 69, 347–361, doi:10.1016/J.CHEMOSPHERE.2007.04.088 (2007).
  • Warner, H. P., Cohen, J. M., & Ireland, J. C.: Determination of Henry’s law constants of selected priority pollutants, Tech. rep., U.S. EPA, Municipal Environmental Research Laboratory, Wastewater Research Division, Cincinnati, Ohio, 45268, USA (1980).
  • Wright, D. A., Sandler, S. I., & DeVoll, D.: Infinite dilution activity coefficients and solubilities of halogenated hydrocarbons in water at ambient temperatures, Environ. Sci. Technol., 26, 1828–1831, doi:10.1021/ES00033A018 (1992).
  • Yaws, C. L., ed.: Chemical Properties Handbook, McGraw-Hill, Inc. (1999).
  • Yaws, C. L. & Yang, H.-C.: Henry’s law constant for compound in water, in: Thermodynamic and Physical Property Data, edited by Yaws, C. L., pp. 181–206, Gulf Publishing Company, Houston, TX (1992).
  • Yurteri, C., Ryan, D. F., Callow, J. J., & Gurol, M. D.: The effect of chemical composition of water on Henry’s law constant, J. Water Pollut. Control Fed., 59, 950–956 (1987).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
19) Value at T = 310 K.
31) Value at T = 295 K.
66) Value at T = 275 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
103) The value is most probably taken from the report by Howe et al. (1987).
116) Value given here as quoted by Staudinger and Roberts (1996).
126) Value at T = 296 K.
127) Solubility in sea water.
248) The same data were also published in McConnell et al. (1975).
249) Values at different temperatures are from different sources. Thus a temperature dependence was not calculated.
250) Chiang et al. (1998) show vinyl chloride in their Table 2 but most probably they meant to refer to dichloromethane instead.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

* * *

Search Henry's Law Database

Species Search:

Identifier Search:

Reference Search:

* * *

Convert Henry's Law Constants

Convert:

* * *