When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
A new version is currently under peer review:
R. Sander: Compilation of Henry's law constants (version 5.0.0-rc.0)
for water as solvent,
doi:10.5194/egusphere-2023-1584
The database on this web page will be updated to
version 5.0.0 when the peer review of the manuscript is completed.
|
| FORMULA: | HgCl2 |
|
CAS RN: | 7487-94-7 |
STRUCTURE
(FROM
NIST):
|
|
|
InChIKey: | LWJROJCJINYWOX-UHFFFAOYSA-L |
|
|
References |
Type |
Notes |
| [mol/(m3Pa)] |
[K] |
|
|
|
| 1.0×103 |
|
Severit (1997) |
M |
87)
|
| 1.6×104 |
|
Abraham et al. (2008) |
V |
|
| 4.2×104 |
|
Abraham et al. (2008) |
V |
|
| 1.3×104 |
7400 |
Kanefke (2008) |
R |
|
| 2.4×105 |
|
Shon et al. (2005) |
C |
|
| 1.4×104 |
5300 |
WHO (1990) |
C |
|
| 1.4×104 |
5300 |
Lindqvist and Rodhe (1985) |
C |
|
| 4.2×104 |
7400 |
Abraham et al. (2008) |
Q |
88)
|
| 2.7×104 |
|
Schroeder and Munthe (1998) |
? |
7)
9)
|
| 1.4×104 |
9500 |
Braun and Dransfeld (1989) |
? |
89)
|
| 6.3×102 |
|
Iverfeldt and Persson (1985) |
? |
90)
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Abraham, M. H., Gil-Lostes, J., Acree, Jr., W. E., Cometto-Muñiz, J. E., & Cain, W. S.: Solvation parameters for mercury and mercury(II) compounds: calculation of properties of environmental interest, J. Environ. Monit., 10, 435–442, doi:10.1039/B719685G (2008).
-
Braun, H. & Dransfeld, P.: Abscheidung von Quecksilber, gVC/VDI-Tagung “Entsorgung von Sonderabfällen durch Verbrennung”, Baden-Baden, 4-6 Dec 1989 (1989).
-
Iverfeldt, Å. & Persson, I.: The solvation thermodynamics of methylmercury(II) species derived from measurements of the heat of solution and the Henry’s law constant, Inorg. Chim. Acta, 103, 113–119, doi:10.1016/S0020-1693(00)87476-9 (1985).
-
Kanefke, R.: Durch Quecksilberbromierung verbesserte Quecksilberabscheidung aus den Abgasen von Kohlekraftwerken und Abfallverbrennungsanlagen, Ph.D. thesis, Martin-Luther-Universität Halle-Wittenberg, Germany (2008).
-
Lindqvist, O. & Rodhe, H.: Atmospheric mercury – a review, Tellus, 37B, 136–159, doi:10.1111/J.1600-0889.1985.TB00062.X (1985).
-
Schroeder, W. H. & Munthe, J.: Atmospheric mercury – An overview, Atmos. Environ., 32, 809–822, doi:10.1016/S1352-2310(97)00293-8 (1998).
-
Severit, P.: Experimentelle Untersuchung der Desorption von Quecksilber und Quecksilberverbindungen aus wässrigen Lösungen, diplomarbeit, Universität Köln, Germany (1997).
-
Shon, Z.-H., Kim, K.-H., Kim, M.-Y., & Lee, M.: Modeling study of reactive gaseous mercury in the urban air, Atmos. Environ., 39, 749–761, doi:10.1016/J.ATMOSENV.2004.09.071 (2005).
-
WHO: Environmental Health Criteria 101 – methylmercury, Tech. rep., World Health Organization, URL http://www.inchem.org/documents/ehc/ehc/ehc101.htm (1990).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
| 7) |
Several references are given in the list of Henry's law constants but not assigned to specific species. |
| 9) |
Value at T = 293 K. |
| 87) |
Value at T = 333 K. |
| 88) |
Calculated using linear free energy relationships (LFER). |
| 89) |
Measured at high temperature and extrapolated to T⊖ = 298.15 K. |
| 90) |
More than one reference is given as the source of this value. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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