When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 5.0.0) for
water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023),
doi:10.5194/acp-23-10901-2023
The publication from 2023 replaces that from 2015,
which is now obsolete. Please do not cite the old paper anymore.
|
| FORMULA: | HgCl2 |
|
CAS RN: | 7487-94-7 |
STRUCTURE
(FROM
NIST):
|
|
|
InChIKey: | LWJROJCJINYWOX-UHFFFAOYSA-L |
|
|
References |
Type |
Notes |
| [mol/(m3Pa)] |
[K] |
|
|
|
| 1.0×103 |
|
Severit (1997) |
M |
218)
|
| 1.6×104 |
|
Abraham et al. (2008) |
V |
|
| 4.2×104 |
|
Abraham et al. (2008) |
V |
|
| 1.3×104 |
7400 |
Kanefke (2008) |
R |
|
| 2.4×105 |
|
Shon et al. (2005) |
C |
|
| 1.4×104 |
5300 |
WHO (1990) |
C |
|
| 1.4×104 |
5300 |
Lindqvist and Rodhe (1985) |
C |
|
| 4.2×104 |
7400 |
Abraham et al. (2008) |
Q |
219)
|
| 2.7×104 |
|
Schroeder and Munthe (1998) |
? |
12)
21)
|
| 1.4×104 |
9500 |
Braun and Dransfeld (1989) |
? |
11)
|
| 6.3×102 |
|
Iverfeldt and Persson (1985) |
? |
220)
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Abraham, M. H., Gil-Lostes, J., Acree, Jr., W. E., Cometto-Muñiz, J. E., & Cain, W. S.: Solvation parameters for mercury and mercury(II) compounds: calculation of properties of environmental interest, J. Environ. Monit., 10, 435–442, doi:10.1039/B719685G (2008).
-
Braun, H. & Dransfeld, P.: Abscheidung von Quecksilber, GVC/VDI-Tagung “Entsorgung von Sonderabfällen durch Verbrennung”, Baden-Baden, 4–6 Dec 1989 (1989).
-
Iverfeldt, Å. & Persson, I.: The solvation thermodynamics of methylmercury(II) species derived from measurements of the heat of solution and the Henry’s law constant, Inorg. Chim. Acta, 103, 113–119, doi:10.1016/S0020-1693(00)87476-9 (1985).
-
Kanefke, R.: Durch Quecksilberbromierung verbesserte Quecksilberabscheidung aus den Abgasen von Kohlekraftwerken und Abfallverbrennungsanlagen, Ph.D. thesis, Martin-Luther-Universität Halle-Wittenberg, Germany, ISBN 978-3-8322-7241-8 (2008).
-
Lindqvist, O. & Rodhe, H.: Atmospheric mercury – a review, Tellus, 37B, 136–159, doi:10.1111/J.1600-0889.1985.TB00062.X (1985).
-
Schroeder, W. H. & Munthe, J.: Atmospheric mercury – An overview, Atmos. Environ., 32, 809–822, doi:10.1016/S1352-2310(97)00293-8 (1998).
-
Severit, P.: Experimentelle Untersuchung der Desorption von Quecksilber und Quecksilberverbindungen aus wässrigen Lösungen, Diplomarbeit, Universität Köln, Germany (1997).
-
Shon, Z.-H., Kim, K.-H., Kim, M.-Y., & Lee, M.: Modeling study of reactive gaseous mercury in the urban air, Atmos. Environ., 39, 749–761, doi:10.1016/J.ATMOSENV.2004.09.071 (2005).
-
WHO: Environmental Health Criteria 101 – methylmercury, Tech. rep., World Health Organization, URL https://www.inchem.org/documents/ehc/ehc/ehc101.htm (1990).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2023) for further details.
Notes
| 11) |
Measured at high temperature and extrapolated to T⊖ = 298.15 K. |
| 12) |
Value at T = 293 K. |
| 21) |
Several references are given in the list of Henry's law constants but not assigned to specific species. |
| 218) |
Value at T = 333 K. |
| 219) |
Calculated using linear free energy relationships (LFERs). |
| 220) |
More than one reference is given as the source of this value. |
The numbers of the notes are the same as
in Sander (2023). References cited in the notes can be
found here.
|
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