When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
A new version is currently under peer review:
R. Sander: Compilation of Henry's law constants (version 5.0.0-rc.0)
for water as solvent,
doi:10.5194/egusphere-2023-1584
The database on this web page will be updated to
version 5.0.0 when the peer review of the manuscript is completed.
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References |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
4.4×10−5 |
2200 |
Fernández-Prini et al. (2003) |
L |
1)
|
4.3×10−5 |
2300 |
Abraham and Matteoli (1988) |
L |
|
4.2×10−5 |
2200 |
Wilhelm et al. (1977) |
L |
|
3.3×10−5 |
|
Steward et al. (1973) |
L |
19)
|
4.3×10−5 |
2300 |
Krause and Benson (1989) |
M |
|
4.2×10−5 |
2400 |
Crovetto et al. (1982) |
M |
|
4.3×10−5 |
1900 |
Morrison and Johnstone (1954) |
M |
|
4.3×10−5 |
2300 |
Clever (1979b) |
X |
5)
|
4.9×10−5 |
2500 |
Dean (1992) |
? |
6)
|
4.3×10−5 |
|
Abraham et al. (1990) |
? |
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Abraham, M. H. & Matteoli, E.: The temperature variation of the hydrophobic effect, J. Chem. Soc. Faraday Trans. 1, 84, 1985–2000, doi:10.1039/F19888401985 (1988).
-
Abraham, M. H., Whiting, G. S., Fuchs, R., & Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291–300, doi:10.1039/P29900000291 (1990).
-
Clever, H. L., ed.: IUPAC Solubility Data Series, vol. 2 of Krypton, Xenon and Radon, Pergamon Press, Oxford, England (1979b).
-
Crovetto, R., Fernández-Prini, R., & Japas, M. L.: Solubilities of inert gases and methane in H2O and in D2O in the temperature range of 300 to 600 K, J. Chem. Phys., 76, 1077–1086, doi:10.1063/1.443074 (1982).
-
Dean, J. A.: Lange’s Handbook of Chemistry, McGraw-Hill, Inc. (1992).
-
Fernández-Prini, R., Alvarez, J. L., & Harvey, A. H.: Henry’s constants and vapor-liquid distribution constants for gaseous solutes in H2O and D2O at high temperatures, J. Phys. Chem. Ref. Data, 32, 903–916, doi:10.1063/1.1564818 (2003).
-
Krause, Jr., D. & Benson, B. B.: The solubility and isotopic fractionation of gases in dilute aqueous solution. IIa. solubilities of the noble gases, J. Solution Chem., 18, 823–873, doi:10.1007/BF00685062 (1989).
-
Morrison, T. J. & Johnstone, N. B.: Solubilities of the inert gases in water, J. Chem. Soc., pp. 3441–3446, doi:10.1039/JR9540003441 (1954).
-
Steward, A., Allott, P. R., Cowles, A. L., & Mapleson, W. W.: Solubility coefficients for inhaled anaesthetics for water, oil and biological media, Br. J. Anaesth., 45, 282–293, doi:10.1093/BJA/45.3.282 (1973).
-
Wilhelm, E., Battino, R., & Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219–262, doi:10.1021/CR60306A003 (1977).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
1) |
Vapor pressure data for water from Wagner and Pruss (1993) was needed to calculate Hs. |
5) |
Value given here as quoted by Lide and Frederikse (1995). |
6) |
Only the tabulated data between T = 273 K and T = 303 K from Dean (1992) were used to derive Hs and its temperature dependence. Above T = 303 K, the tabulated data could not be parameterized very well. The partial pressure of water vapor (needed to convert some Henry's law constants) was calculated using the formula given by Sander et al. (1995). The quantities A and α from Dean (1992) were assumed to be identical. |
19) |
Value at T = 310 K. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
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