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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsHydrocarbons (C, H)Mononuclear aromatics → benzene

FORMULA:C6H6
CAS RN:71-43-2
STRUCTURE
(FROM NIST):
InChIKey:UHOVQNZJYSORNB-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.7×10−3 4200 Staudinger and Roberts (2001) L
1.6×10−3 4100 Staudinger and Roberts (1996) L
1.8×10−3 Mackay and Shiu (1981) L
1.7×10−3 Kim and Kim (2014) M
1.8×10−3 3800 Hiatt (2013) M
3.5×10−3 Zhang et al. (2013) M
1.4×10−3 2400 Lau et al. (2010) M 89)
1.7×10−3 4200 Sieg et al. (2009) M 121)
1.8×10−3 Li et al. (2008) M
2.5×10−3 Lodge and Danso (2007) M
1.4×10−3 2200 Lei et al. (2004) M 122)
Cheng et al. (2003) M 123)
1.8×10−3 Karl et al. (2003) M 31)
1.8×10−3 4200 Bakierowska and Trzeszczyński (2003) M
1.8×10−3 3700 Görgényi et al. (2002) M
1.9×10−3 3200 Bierwagen and Keller (2001) M
2.1×10−3 Kochetkov et al. (2001) M 115) 124)
1.7×10−3 Kochetkov et al. (2001) M 115) 125)
1.8×10−3 Miller and Stuart (2000) M 126)
3.7×10−3 Altschuh et al. (1999) M
1.7×10−3 Ryu and Park (1999) M
1.8×10−3 Dohnal and Hovorka (1999) M
1.8×10−3 Allen et al. (1998) M
2.2×10−3 Peng and Wan (1998) M
1.4×10−3 3300 Peng and Wan (1998) M 127)
2.2×10−3 de Wolf and Lieder (1998) M 31)
1.9×10−3 3200 Peng and Wan (1997) M
1.8×10−3 2700 Kondoh and Nakajima (1997) M
1.4×10−3 3300 Park et al. (1997) M
1.8×10−3 4200 Alaee et al. (1996) M
1.6×10−3 4300 Turner et al. (1996) M
2.1×10−3 3900 Dewulf et al. (1995) M
2.0×10−3 Nielsen et al. (1994) M
1.7×10−3 4000 Khalfaoui and Newsham (1994b) M
1.9×10−3 3800 Robbins et al. (1993) M
1.7×10−3 Hoff et al. (1993) M
1.8×10−3 2300 Ettre et al. (1993) M 89)
1.5×10−3 Hansen et al. (1993) M 128)
1.7×10−3 4000 Perlinger et al. (1993) M
1.7×10−3 Li and Carr (1993) M
1.8×10−3 Li et al. (1993) M
1.5×10−3 Zhang and Pawliszyn (1993) M
1.7×10−3 4000 Cooling et al. (1992) M
1.8×10−3 Anderson (1992) M 126)
1.6×10−3 4300 Bissonette et al. (1990) M
2.0×10−3 Guitart et al. (1989) M 19)
1.8×10−3 3200 Ashworth et al. (1988) M 103)
1.7×10−3 Keeley et al. (1988) M
2.0×10−3 Hellmann (1987) M 31)
1.3×10−3 Yurteri et al. (1987) M 9)
1.8×10−3 3600 Tsonopoulos and Wilson (1983) M
1.7×10−3 3900 Sanemasa et al. (1982) M
1.8×10−3 4000 Leighton and Calo (1981) M
1.7×10−3 3500 Sanemasa et al. (1981) M
1.2×10−3 5300 Ervin et al. (1980) M
1.8×10−3 Warner et al. (1980) M
1.8×10−3 Mackay et al. (1979) M
1.1×10−3 Sato and Nakajima (1979a) M 19)
1.6×10−3 3800 Tsibul’skii et al. (1979) M
1.8×10−3 4200 Green and Frank (1979) M
1.8×10−3 Vitenberg et al. (1975) M
1.2×10−3 Vitenberg et al. (1974) M 9)
1.7×10−3 4400 Brown and Wasik (1974) M
2.1×10−3 4500 Hartkopf and Karger (1973) M
1.6×10−3 4500 Wasik and Tsang (1970) M
1.5×10−3 Saylor et al. (1938) M 23)
3.5×10−4 Abraham and Acree (2007) V
1.8×10−3 Mackay et al. (2006a) V
1.8×10−3 Kochetkov et al. (2001) V
1.8×10−3 Shiu and Ma (2000) V
1.8×10−3 Shiu and Mackay (1997) V
1.8×10−3 Park et al. (1997) V
1.8×10−3 Mackay et al. (1992a) V
1.8×10−3 Hwang et al. (1992) V
1.8×10−3 Eastcott et al. (1988) V
1.8×10−3 3800 Abraham (1984) V
1.8×10−3 3600 Ben-Naim and Wilf (1980) V
1.8×10−3 Warner et al. (1980) V
1.8×10−3 Hine and Mookerjee (1975) V
1.8×10−3 4100 Mackay and Leinonen (1975) V
1.8×10−3 3800 Andon et al. (1954) V 129)
1.8×10−3 Bohon and Claussen (1951) V
1.8×10−3 Mackay et al. (1979) T
3800 Gill et al. (1976) T 100)
1.8×10−3 2200 Goldstein (1982) X 116)
1.8×10−3 Sieg et al. (2008) C
1.8×10−3 Schüürmann (2000) C 7)
1.8×10−3 Smith et al. (1993) C 9)
1.8×10−3 Ryan et al. (1988) C
1.8×10−3 Shen (1982) C
1.7×10−3 Hilal et al. (2008) Q
4000 Kühne et al. (2005) Q
2.2×10−3 Nirmalakhandan and Speece (1988a) Q
1.8×10−3 Arbuckle (1983) Q
3700 Kühne et al. (2005) ?
1.8×10−3 Yaws and Yang (1992) ? 92)
1.8×10−3 Abraham et al. (1990) ?
2.2×10−3 Mackay and Yeun (1983) ?

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Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

7) Several references are given in the list of Henry's law constants but not assigned to specific species.
9) Value at T = 293 K.
19) Value at T = 310 K.
23) Value at T = 303 K.
31) Value at T = 295 K.
89) Measured at high temperature and extrapolated to T = 298.15 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
100) Calculated from the solvation enthalpy, using the van 't Hoff equation.
103) The value is most probably taken from the report by Howe et al. (1987).
115) Value at T = 301 K.
116) Value given here as quoted by Staudinger and Roberts (1996).
121) Sieg et al. (2009) also provide data for supercooled water. Here, only data above 0 °C were used to calculate the temperature dependence.
122) Extrapolated from data above 298 K.
123) It was found that Hs changes with the concentration of the solution.
124) Value obtained by applying a modified batch air-stripping method, otherwise called the vapor entry loop (VEL) method, see Kochetkov et al. (2001) for details.
125) Value obtained by applying the static head space (HS) method, see Kochetkov et al. (2001) for details.
126) Value at T = 296 K.
127) Solubility in sea water.
128) Value at T = 302 K.
129) Calculated using Gh and Hh from Table 2 in Andon et al. (1954). Note that the thermodynamic functions in that table are not based on their α in Table 1. Instead, the expression exp(−Gh/(RT)) yields the Henry's law constant Hsxp in the unit 1/atm.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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