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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with chlorine (Cl)Chlorocarbons (C, H, Cl) → trichloromethane

FORMULA:CHCl3
TRIVIAL NAME: chloroform
CAS RN:67-66-3
STRUCTURE
(FROM NIST):
InChIKey:HEDRZPFGACZZDS-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.5×10−3 4500 Sander et al. (2011) L
2.6×10−3 4300 Warneck (2007) L
2.5×10−3 4500 Sander et al. (2006) L
2.5×10−3 4500 Staudinger and Roberts (2001) L
2.5×10−3 4500 Staudinger and Roberts (1996) L
2.6×10−3 Mackay and Shiu (1981) L
1.6×10−3 Steward et al. (1973) L 19)
2.8×10−3 4500 Hiatt (2013) M
2.5×10−3 3900 Chen et al. (2012) M
1.4×10−3 Zhang et al. (2002) M 19)
2.6×10−3 4100 Görgényi et al. (2002) M
2.0×10−3 4600 Moore (2000) M 127)
2.4×10−3 David et al. (2000) M 126)
2.7×10−3 Ryu and Park (1999) M
3.0×10−3 Dohnal and Hovorka (1999) M 9)
3.0×10−3 Chiang et al. (1998) M 9)
3.2×10−3 Hovorka and Dohnal (1997) M 9)
2.7×10−3 3400 Kondoh and Nakajima (1997) M
2.6×10−3 3400 Park et al. (1997) M
2.2×10−3 4700 Turner et al. (1996) M
2.2×10−3 4100 Moore et al. (1995) M 127)
2.6×10−3 4400 Dewulf et al. (1995) M
2.5×10−3 Hoff et al. (1993) M
2.4×10−3 Li et al. (1993) M
2.6×10−3 3900 Wright et al. (1992) M
4.8×10−3 7300 Tancrède and Yanagisawa (1990) M
2.4×10−3 2000 Lamarche and Droste (1989) M 135)
2.1×10−3 Guitart et al. (1989) M 19)
2.3×10−3 5000 Ashworth et al. (1988) M 103)
2.7×10−3 4600 Gossett (1987) M
2.6×10−3 4300 Munz and Roberts (1987) M
2.9×10−3 Hellmann (1987) M 31)
3.3×10−3 Munz and Roberts (1986) M
2.5×10−3 4300 Gossett et al. (1985) M
2.5×10−3 5200 Nicholson et al. (1984) M
2.3×10−3 4200 Lincoff and Gossett (1984) M
2.0×10−3 3900 Hunter-Smith et al. (1983) M 127) 251)
2.5×10−3 4000 Leighton and Calo (1981) M
1.5×10−3 5600 Ervin et al. (1980) M
2.9×10−3 Warner et al. (1980) M
2.4×10−3 7200 Balls (1980) M
1.4×10−3 Sato and Nakajima (1979b) M 19)
3.5×10−3 Pearson and McConnell (1975) M 9) 248)
2.8×10−3 5100 Hartkopf and Karger (1973) M
2.6×10−3 4600 Rex (1906) M
2.6×10−3 Mackay et al. (2006b) V
2.6×10−3 4400 Fogg and Sangster (2003) V
2.5×10−3 Park et al. (1997) V
2.6×10−3 Mackay et al. (1993) V
2.6×10−3 Hwang et al. (1992) V
5.5×10−3 McLachlan et al. (1990) V 147)
3.1×10−3 Warner et al. (1980) V
2.5×10−3 Dilling (1977) V 249)
9.0×10−3 Dilling (1977) V 66)
2.3×10−3 Hine and Mookerjee (1975) V
2.5×10−3 Dilling et al. (1975) V
2.2×10−3 4700 Winkler (1906) V
2.5×10−3 4100 Barr and Newsham (1987) X 116)
3.0×10−3 4400 Goldstein (1982) X 116)
2.4×10−3 Harrison et al. (1993) C
3.4×10−3 Harrison et al. (1993) C
3.4×10−3 Ryan et al. (1988) C
2.7×10−3 Nicholson et al. (1984) C
2.1×10−3 Nicholson et al. (1984) C 9)
2.9×10−3 Shen (1982) C
3.1×10−3 Dilling (1977) C
3.1×10−3 Dilling et al. (1975) C
3.2×10−3 Hilal et al. (2008) Q
3300 Kühne et al. (2005) Q
3.9×10−3 Nirmalakhandan and Speece (1988a) Q
2.3×10−3 Arbuckle (1983) Q
2.3×10−3 Mackay et al. (2006b) ?
4300 Kühne et al. (2005) ?
2.4×10−3 Yaws (1999) ?
2.3×10−3 Mackay et al. (1993) ?
2.4×10−3 Yaws and Yang (1992) ? 92)
2.5×10−3 Abraham et al. (1990) ?

References

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  • Hwang, Y.-L., Olson, J. D., & Keller, II, G. E.: Steam stripping for removal of organic pollutants from water. 2. Vapor-liquid equilibrium data, Ind. Eng. Chem. Res., 31, 1759–1768, doi:10.1021/IE00007A022 (1992).
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Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
19) Value at T = 310 K.
31) Value at T = 295 K.
66) Value at T = 275 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
103) The value is most probably taken from the report by Howe et al. (1987).
116) Value given here as quoted by Staudinger and Roberts (1996).
126) Value at T = 296 K.
127) Solubility in sea water.
135) The temperature dependence is recalculated using the data in Table 4 of Lamarche and Droste (1989) and not taken from their Table 5.
147) Value at T = 283 K.
248) The same data were also published in McConnell et al. (1975).
249) Values at different temperatures are from different sources. Thus a temperature dependence was not calculated.
251) Probably an interpolation of the data from Balls (1980).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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