When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
FORMULA: | C6H5COOH |
TRIVIAL NAME:
|
benzoic acid
|
CAS RN: | 65-85-0 |
STRUCTURE
(FROM
NIST):
|
|
InChIKey: | WPYMKLBDIGXBTP-UHFFFAOYSA-N |
|
|
References |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
2.9×102 |
|
Li et al. (2007) |
M |
|
2.5×102 |
|
Mackay et al. (2006c) |
V |
|
1.4×102 |
|
Lide and Frederikse (1995) |
V |
|
2.1 |
|
Mackay et al. (1995) |
V |
|
1.7×102 |
|
Meylan and Howard (1991) |
V |
|
1.4×102 |
6500 |
Goldstein (1982) |
X |
116)
|
1.4×102 |
|
Howard (1989) |
X |
164)
|
2.4×102 |
|
Hilal et al. (2008) |
Q |
|
|
6700 |
Kühne et al. (2005) |
Q |
|
9.1×101 |
|
Meylan and Howard (1991) |
Q |
|
|
6200 |
Kühne et al. (2005) |
? |
|
2.4×102 |
|
Yaws and Yang (1992) |
? |
92)
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Goldstein, D. J.: Air and steam stripping of toxic pollutants, Appendix 3: Henry’s law constants, Tech. Rep. EPA-68-03-002, Industrial Environmental Research Laboratory, Cincinnati, OH, USA (1982).
-
Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
-
Howard, P. H.: Handbook of Environmental fate and exposure data for organic chemicals. Vol. I: Large production and priority pollutants, Lewis Publishers Inc. Chelsea, Michigan (1989).
-
Kühne, R., Ebert, R.-U., & Schüürmann, G.: Prediction of the temperature dependency of Henry’s law constant from chemical structure, Environ. Sci. Technol., 39, 6705–6711, doi:10.1021/ES050527H (2005).
-
Lide, D. R. & Frederikse, H. P. R., eds.: CRC Handbook of Chemistry and Physics, 76th Edition, CRC Press, Inc., Boca Raton, FL (1995).
-
Li, H., Ellis, D., & Mackay, D.: Measurement of low air-water partition coefficients of organic acids by evaporation from a water surface, J. Chem. Eng. Data, 52, 1580–1584, doi:10.1021/JE600556D (2007).
-
Mackay, D., Shiu, W. Y., & Ma, K. C.: Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Oxygen, Nitrogen, and Sulfur Containing Compounds, Lewis Publishers, Boca Raton (1995).
-
Mackay, D., Shiu, W. Y., Ma, K. C., & Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. III of Oxygen Containing Compounds, CRC/Taylor & Francis Group (2006c).
-
Meylan, W. M. & Howard, P. H.: Bond contribution method for estimating Henry’s law constants, Environ. Toxicol. Chem., 10, 1283–1293, doi:10.1002/ETC.5620101007 (1991).
-
Yaws, C. L. & Yang, H.-C.: Henry’s law constant for compound in water, in: Thermodynamic and Physical Property Data, edited by Yaws, C. L., pp. 181–206, Gulf Publishing Company, Houston, TX (1992).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
92) |
Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species. |
116) |
Value given here as quoted by Staudinger and Roberts (1996). |
164) |
Value given here as quoted by Mackay et al. (1995). |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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