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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with chlorine (Cl)Oxygenated chlorocarbons (C, H, O, Cl) → dieldrin

FORMULA:C12H8OCl6
CAS RN:60-57-1
STRUCTURE
(FROM NIST):
InChIKey:DFBKLUNHFCTMDC-NLUYNBKHSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.0 Shen and Wania (2005) L 143)
9.1×10−1 Shen and Wania (2005) L 144)
9.1×10−1 Mackay and Shiu (1981) L
9.2×10−1 5800 Cetin et al. (2006) M
9.8×10−1 Altschuh et al. (1999) M
3.4×10−1 Slater and Spedding (1981) M 9)
1.7×10−1 Warner et al. (1980) M
8.9×10−1 Mackay et al. (2006d) V
8.9×10−1 Suntio et al. (1988) V 9)
4.9×101 Mackay and Leinonen (1975) V
1.7×10−1 Hilal et al. (2008) C
5.0×101 Suntio et al. (1988) C 9)
2.2×101 Suntio et al. (1988) C 255)
9.8×10−1 Suntio et al. (1988) C 255)
1.7×10−1 Suntio et al. (1988) C
4.7×10−2 Suntio et al. (1988) C
1.3 Ryan et al. (1988) C
1.7×10−1 Shen (1982) C
1.1 Hilal et al. (2008) Q
1.2 MacBean (2012a) ?
5.7×101 Brimblecombe (1986) ? 28)

References

  • Altschuh, J., Brüggemann, R., Santl, H., Eichinger, G., & Piringer, O. G.: Henry’s law constants for a diverse set of organic chemicals: Experimental determination and comparison of estimation methods, Chemosphere, 39, 1871–1887, doi:10.1016/S0045-6535(99)00082-X (1999).
  • Brimblecombe, P.: Air Composition & Chemistry, Cambridge University Press, Cambridge (1986).
  • Cetin, B., Ozer, S., Sofuoglu, A., & Odabasi, M.: Determination of Henry’s law constants of organochlorine pesticides in deionized and saline water as a function of temperature, Atmos. Environ., 40, 4538–4546, doi:10.1016/J.ATMOSENV.2006.04.009 (2006).
  • Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
  • MacBean, C.: The Pesticide Manual, 16th Edition, Supplementary Entries - Extended, Tech. rep., British Crop Production Council (2012a).
  • Mackay, D. & Leinonen, P. J.: Rate of evaporation of low-solubility contaminants from water bodies to atmosphere, Environ. Sci. Technol., 9, 1178–1180, doi:10.1021/ES60111A012 (1975).
  • Mackay, D. & Shiu, W. Y.: A critical review of Henry’s law constants for chemicals of environmental interest, J. Phys. Chem. Ref. Data, 10, 1175–1199, doi:10.1063/1.555654 (1981).
  • Mackay, D., Shiu, W. Y., Ma, K. C., & Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides, CRC/Taylor & Francis Group (2006d).
  • Ryan, J. A., Bell, R. M., Davidson, J. M., & O’Connor, G. A.: Plant uptake of non-ionic organic chemicals from soils, Chemosphere, 17, 2299–2323, doi:10.1016/0045-6535(88)90142-7 (1988).
  • Shen, T. T.: Estimation of organic compound emissions from waste lagoons, J. Air Pollut. Control Assoc., 32, 79–82, doi:10.1080/00022470.1982.10465374 (1982).
  • Shen, L. & Wania, F.: Compilation, evaluation, and selection of physical-chemical property data for organochlorine pesticides, J. Chem. Eng. Data, 50, 742–768, doi:10.1021/JE049693F (2005).
  • Slater, R. M. & Spedding, D. J.: Transport of dieldrin between air and water, Arch. Environ. Contam. Toxicol., 10, 25–33, doi:10.1007/BF01057572 (1981).
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., & Glotfelty, D.: Critical review of Henry’s law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1–59, doi:10.1007/978-1-4612-3850-8_1 (1988).
  • Warner, H. P., Cohen, J. M., & Ireland, J. C.: Determination of Henry’s law constants of selected priority pollutants, Tech. rep., U.S. EPA, Municipal Environmental Research Laboratory, Wastewater Research Division, Cincinnati, Ohio, 45268, USA (1980).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
28) Value at T = 288 K.
143) Literature-derived value.
144) Final adjusted value.
255) Value for T = 293... 298 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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