When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
FORMULA: | C2H5OC2H5 |
CAS RN: | 60-29-7 |
STRUCTURE
(FROM
NIST):
|
|
InChIKey: | RTZKZFJDLAIYFH-UHFFFAOYSA-N |
|
|
References |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
5.0×10−3 |
|
Steward et al. (1973) |
L |
19)
|
1.1×10−2 |
6600 |
Hiatt (2013) |
M |
|
9.5×10−2 |
|
Helburn et al. (2008) |
M |
|
1.1×10−2 |
|
Nielsen et al. (1994) |
M |
|
7.0×10−3 |
3900 |
Lamarche and Droste (1989) |
M |
135)
|
6.3×10−3 |
|
Guitart et al. (1989) |
M |
19)
|
7.8×10−3 |
|
Signer et al. (1969) |
M |
|
1.1×10−2 |
|
Mackay et al. (2006c) |
V |
|
1.1×10−2 |
|
Mackay et al. (1993) |
V |
|
8.7×10−3 |
|
Hwang et al. (1992) |
V |
|
1.1×10−2 |
|
Hine and Weimar (1965) |
V |
|
1.1×10−2 |
|
Butler and Ramchandani (1935) |
V |
|
6.0×10−3 |
5700 |
Bagno et al. (1991) |
T |
196)
|
7.0×10−3 |
|
Hilal et al. (2008) |
Q |
|
|
5300 |
Kühne et al. (2005) |
Q |
|
1.7×10−3 |
|
Nirmalakhandan et al. (1997) |
Q |
|
|
5700 |
Kühne et al. (2005) |
? |
|
7.7×10−3 |
|
Hoff et al. (1993) |
? |
7)
|
6.0×10−3 |
|
Abraham et al. (1990) |
? |
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Abraham, M. H., Whiting, G. S., Fuchs, R., & Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291–300, doi:10.1039/P29900000291 (1990).
-
Bagno, A., Lucchini, V., & Scorrano, G.: Thermodynamics of protonation of ketones and esters and energies of hydration of their conjugate acids, J. Phys. Chem., 95, 345–352, doi:10.1021/J100154A063 (1991).
-
Butler, J. A. V. & Ramchandani, C. N.: The solubility of non-electrolytes. Part II. The influence of the polar group on the free energy of hydration of aliphatic compounds, J. Chem. Soc., pp. 952–955, doi:10.1039/JR9350000952 (1935).
-
Guitart, R., Puigdemont, F., & Arboix, M.: Rapid headspace gas chromatographic method for the determination of liquid/gas partition coefficients, J. Chromatogr., 491, 271–280, doi:10.1016/S0378-4347(00)82845-5 (1989).
-
Helburn, R., Albritton, J., Howe, G., Michael, L., & Franke, D.: Henry’s law constants for fragrance and organic solvent compounds in aqueous industrial surfactants, J. Chem. Eng. Data, 53, 1071–1079, doi:10.1021/JE700418A (2008).
-
Hiatt, M. H.: Determination of Henry’s law constants using internal standards with benchmark values, J. Chem. Eng. Data, 58, 902–908, doi:10.1021/JE3010535 (2013).
-
Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
-
Hine, J. & Weimar, Jr., R. D.: Carbon basicity, J. Am. Chem. Soc., 87, 3387–3396, doi:10.1021/JA01093A018 (1965).
-
Hoff, J. T., Mackay, D., Gillham, R., & Shiu, W. Y.: Partitioning of organic chemicals at the air-water interface in environmental systems, Environ. Sci. Technol., 27, 2174–2180, doi:10.1021/ES00047A026 (1993).
-
Hwang, Y.-L., Olson, J. D., & Keller, II, G. E.: Steam stripping for removal of organic pollutants from water. 2. Vapor-liquid equilibrium data, Ind. Eng. Chem. Res., 31, 1759–1768, doi:10.1021/IE00007A022 (1992).
-
Kühne, R., Ebert, R.-U., & Schüürmann, G.: Prediction of the temperature dependency of Henry’s law constant from chemical structure, Environ. Sci. Technol., 39, 6705–6711, doi:10.1021/ES050527H (2005).
-
Lamarche, P. & Droste, R. L.: Air stripping mass transfer correlations for volatile organics, J. Am. Water Works Assoc., 81, 78–89, doi:10.1002/J.1551-8833.1989.TB03326.X (1989).
-
Mackay, D., Shiu, W. Y., & Ma, K. C.: Illustrated Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. III of Volatile Organic Chemicals, Lewis Publishers, Boca Raton (1993).
-
Mackay, D., Shiu, W. Y., Ma, K. C., & Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. III of Oxygen Containing Compounds, CRC/Taylor & Francis Group (2006c).
-
Nielsen, F., Olsen, E., & Fredenslund, A.: Henry’s law constants and infinite dilution activity coefficients for volatile organic compounds in water by a validated batch air stripping method, Environ. Sci. Technol., 28, 2133–2138, doi:10.1021/ES00061A022 (1994).
-
Nirmalakhandan, N., Brennan, R. A., & Speece, R. E.: Predicting Henry’s law constant and the effect of temperature on Henry’s law constant, Wat. Res., 31, 1471–1481, doi:10.1016/S0043-1354(96)00395-8 (1997).
-
Signer, R., Arm, H., & Daenicker, H.: Dampfdrücke, Dichten, thermodynamische Mischfunktionen und Brechungsindices der binären Systeme Wasser-Tetrahydrofuran und Wasser-Diäthyläther bei 25 ∘, Helv. Chim. Acta, 52, 2347–2351, doi:10.1002/HLCA.19690520816 (1969).
-
Steward, A., Allott, P. R., Cowles, A. L., & Mapleson, W. W.: Solubility coefficients for inhaled anaesthetics for water, oil and biological media, Br. J. Anaesth., 45, 282–293, doi:10.1093/BJA/45.3.282 (1973).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
7) |
Several references are given in the list of Henry's law constants but not assigned to specific species. |
19) |
Value at T = 310 K. |
135) |
The temperature dependence is recalculated using the data in Table 4 of Lamarche and Droste (1989) and not taken from their Table 5. |
196) |
Calculated under the assumption that ∆G and ∆H are based on [mol/l] and [atm] as the standard states. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
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