Henry's Law Constants

Rolf Sander

NEW: Version 5.0.0 has been published in October 2023

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Organic species with other elements → Tin (Sn) → tetraethylstannane

FORMULA:	C₈H₂₀Sn
TRIVIAL NAME:	tetraethyltin
CAS RN:	597-64-8
STRUCTURE (FROM NIST):
InChIKey:	RWWNQEOPUOCKGR-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
1.6×10⁻⁵		HSDB (2015)	Q	100)
6.1×10⁻⁶		Abraham et al. (1990)	?
5.7×10⁻⁶	6100	Abraham and Nasehzadeh (1981)	?	824)
1.1×10⁻⁵		Abraham (1979)	?

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Abraham, M. H.: Free energies of solution of rare gases and alkanes in water and nonaqueous solvents. A quantitative assessment of the hydrophobic effect, J. Am. Chem. Soc., 101, 5477–5484, doi:10.1021/JA00513A004 (1979).
Abraham, M. H. & Nasehzadeh, A.: Thermodynamics of solution of gaseous tetramethyltin in 36 solvents. Comparison of experimental results with cavity-theory calculations, J. Chem. Soc. Faraday Trans. 1, 77, 321–339, doi:10.1039/F19817700321 (1981).
Abraham, M. H., Whiting, G. S., Fuchs, R., & Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291–300, doi:10.1039/P29900000291 (1990).
HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), URL https://www.nlm.nih.gov/toxnet/Accessing_HSDB_Content_from_PubChem.html (2015).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

100)	Calculated based on the method by Meylan and Howard (1991).
824)	Wilhelm et al. (1977) and Abraham (1979) are quoted as the source. However, the data cannot be found there.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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Rolf Sander

NEW: Version 5.0.0 has been published in October 2023

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