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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with oxygen (O)Heterocycles with oxygen → 1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane

FORMULA:C10H18O
TRIVIAL NAME: eucalyptol; limonene oxide; 1,8-cineole
CAS RN:470-82-6
STRUCTURE
(FROM NIST):
InChIKey:WEEGYLXZBRQIMU-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
5.9×10−2 Kish et al. (2013) M
5.6×10−2 Fichan et al. (1999) M
1.2×10−1 Amoore and Buttery (1978) M
7.5×10−2 Copolovici and Niinemets (2005) V
2.7×10−2 4600 van Roon et al. (2005) V
7.4×10−2 Niinemets and Reichstein (2002) V
7.8×10−2 Amoore and Buttery (1978) V
2.2×10−2 Hilal et al. (2008) Q

References

  • Amoore, J. E. & Buttery, R. G.: Partition coefficient and comparative olfactometry, Chem. Senses Flavour, 3, 57–71, doi:10.1093/CHEMSE/3.1.57 (1978).
  • Copolovici, L. O. & Niinemets, U.: Temperature dependencies of Henry’s law constants and octanol/water partition coefficients for key plant volatile monoterpenoids, Chemosphere, 61, 1390–1400, doi:10.1016/J.CHEMOSPHERE.2005.05.003 (2005).
  • Fichan, I., Larroche, C., & Gros, J. B.: Water solubility, vapor pressure, and activity coefficients of terpenes and terpenoids, J. Chem. Eng. Data, 44, 56–62, doi:10.1021/JE980070+ (1999).
  • Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
  • Kish, J. D., Leng, C. B., Kelley, J., Hiltner, J., Zhang, Y. H., & Liu, Y.: An improved approach for measuring Henry’s law coefficients of atmospheric organics, Atmos. Environ., 79, 561–565, doi:10.1016/J.ATMOSENV.2013.07.023 (2013).
  • Niinemets, U. & Reichstein, M.: A model analysis of the effects of nonspecific monoterpenoid storage in leaf tissues on emission kinetics and composition in Mediterranean sclerophyllous Quercus species, Global Biogeochem. Cycles, 16, 1110, doi:10.1029/2002GB001927 (2002).
  • van Roon, A., Parsons, J. R., Kloeze, A. M. T., & Govers, H. A. J.: Fate and transport of monoterpenes through soils. Part I. Prediction of temperature dependent soil fate model input-parameters, Chemosphere, 61, 599–609, doi:10.1016/J.CHEMOSPHERE.2005.02.081 (2005).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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