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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with fluorine (F)Organic fluorine → (2,2,2-trifluoroethoxy)-ethene

FORMULA:CF3CH2OCHCH2
TRIVIAL NAME: fluoroxene
CAS RN:406-90-6
STRUCTURE
(FROM NIST):
InChIKey:DLEGDLSLRSOURQ-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
5.4×10−4 4000 Fogg and Sangster (2003) L
3.3×10−4 Steward et al. (1973) L 19)
5.5×10−4 4300 Smith et al. (1981b) M
3.2×10−4 Stoelting and Longshore (1972) M 19)
3.3×10−4 Munson et al. (1964) M 19)
9.5×10−5 Hilal et al. (2008) Q
5.1×10−4 Abraham et al. (1990) ?

References

  • Abraham, M. H., Whiting, G. S., Fuchs, R., & Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291–300, doi:10.1039/P29900000291 (1990).
  • Fogg, P. & Sangster, J.: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, John Wiley & Sons, Inc. (2003).
  • Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
  • Munson, E. S., Saidman, L. J., & Eger, E. I.: Solubility of fluroxene in blood and tissue homogenates, Anesthesiology, 25, 638–640, doi:10.1097/00000542-196409000-00010 (1964).
  • Smith, R. A., Porter, E. G., & Miller, K. W.: The solubility of anesthetic gases in lipid bilayers, Biochim. Biophys. Acta - Biomembranes, 645, 327–338 (1981b).
  • Steward, A., Allott, P. R., Cowles, A. L., & Mapleson, W. W.: Solubility coefficients for inhaled anaesthetics for water, oil and biological media, Br. J. Anaesth., 45, 282–293, doi:10.1093/BJA/45.3.282 (1973).
  • Stoelting, R. K. & Longshore, R. E.: The effects of temperature on fluroxene, halothane, and methoxyflurane blood-gas and cerebrospinal fluid-gas partition coefficients, Anesthesiology, 36, 503–505, doi:10.1097/00000542-197205000-00018 (1972).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

19) Value at T = 310 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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