Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Inorganic species → Hydrogen (H) → hydroxyl radical

FORMULA:	OH
CAS RN:	3352-57-6
STRUCTURE (FROM NIST):
InChIKey:	TUJKJAMUKRIRHC-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
3.8×10⁻¹		Burkholder et al. (2019)	T	47)
3.8×10⁻¹		Burkholder et al. (2015)	T	47)
3.8×10⁻¹		Sander et al. (2011)	T	47)
3.8×10⁻¹		Sander et al. (2006)	T	47)
2.9×10⁻¹	4300	Hanson et al. (1992)	T
3.2×10⁻¹		Mozurkewich (1986)	T
2.9×10⁻¹	3100	Berdnikov and Bazhin (1970)	T	48)
2.5×10⁻¹		Lelieveld and Crutzen (1991)	C
2.0		Lelieveld and Crutzen (1991)	C
8.9×10¹		Lelieveld and Crutzen (1991)	C
2.5×10⁻¹	5300	Jacob (1986)	C	49)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Berdnikov, V. M. & Bazhin, N. M.: Oxidation-reduction potentials of certain inorganic radicals in aqueous solutions, Russ. J. Phys. Chem., 44, 395–398 (1970).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18, JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2015).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C., Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Percival, C. J., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2019).
Hanson, D. R., Burkholder, J. B., Howard, C. J., & Ravishankara, A. R.: Measurement of OH and HO₂ radical uptake coefficients on water and sulfuric acid surfaces, J. Phys. Chem., 96, 4979–4985, doi:10.1021/J100191A046 (1992).
Jacob, D. J.: Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, J. Geophys. Res., 91, 9807–9826, doi:10.1029/JD091ID09P09807 (1986).
Lelieveld, J. & Crutzen, P. J.: The role of clouds in tropospheric photochemistry, J. Atmos. Chem., 12, 229–267, doi:10.1007/BF00048075 (1991).
Mozurkewich, M.: Comment on “Possible role of NO₃ in the nighttime chemistry of a cloud” by William L. Chameides, J. Geophys. Res., 91, 14 569–14 570, doi:10.1029/JD091ID13P14569 (1986).
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL https://jpldataeval.jpl.nasa.gov (2006).
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2011).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

47)	The free energy of solution was calculated based on electrochemical reduction potentials and related free energies.
48)	Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit.
49)	Jacob (1986) assumed the temperature dependence to be the same as for water.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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