When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
A new version is currently under peer review:
R. Sander: Compilation of Henry's law constants (version 5.0.0-rc.0)
for water as solvent,
doi:10.5194/egusphere-2023-1584
The database on this web page will be updated to
version 5.0.0 when the peer review of the manuscript is completed.
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|
|
References |
Type |
Notes |
| [mol/(m3Pa)] |
[K] |
|
|
|
| 3.8×10−1 |
|
Sander et al. (2011) |
L |
|
| 3.8×10−1 |
|
Sander et al. (2006) |
L |
|
| 2.9×10−1 |
4300 |
Hanson et al. (1992) |
T |
|
| 3.2×10−1 |
|
Mozurkewich (1986) |
T |
|
| 2.9×10−1 |
3100 |
Berdnikov and Bazhin (1970) |
T |
11)
|
| 2.5×10−1 |
|
Lelieveld and Crutzen (1991) |
C |
|
| 2.0 |
|
Lelieveld and Crutzen (1991) |
C |
|
| 8.9×101 |
|
Lelieveld and Crutzen (1991) |
C |
|
| 2.5×10−1 |
5300 |
Jacob (1986) |
C |
12)
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Berdnikov, V. M. & Bazhin, N. M.: Oxidation-reduction potentials of certain inorganic radicals in aqueous solutions, Russ. J. Phys. Chem., 44, 395–398 (1970).
-
Hanson, D. R., Burkholder, J. B., Howard, C. J., & Ravishankara, A. R.: Measurement of OH and HO2 radical uptake coefficients on water and sulfuric acid surfaces, J. Phys. Chem., 96, 4979–4985, doi:10.1021/J100191A046 (1992).
-
Jacob, D. J.: Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, J. Geophys. Res., 91D, 9807–9826, doi:10.1029/JD091ID09P09807 (1986).
-
Lelieveld, J. & Crutzen, P. J.: The role of clouds in tropospheric photochemistry, J. Atmos. Chem., 12, 229–267, doi:10.1007/BF00048075 (1991).
-
Mozurkewich, M.: Comment on “Possible role of NO3 in the nighttime chemistry of a cloud” by William L. Chameides, J. Geophys. Res., 91D, 14 569–14 570, doi:10.1029/JD091ID13P14569 (1986).
-
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL http://jpldataeval.jpl.nasa.gov (2006).
-
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL http://jpldataeval.jpl.nasa.gov (2011).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
| 11) |
Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit. |
| 12) |
Jacob (1986) assumed the temperature dependence to be the same as for water. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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