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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with chlorine (Cl)Chlorocarbons (C, H, Cl) → β-1,2,3,4,5,6-hexachlorocyclohexane

FORMULA:C6H6Cl6
TRIVIAL NAME: β-lindane; β-HCH
CAS RN:319-85-7
STRUCTURE
(FROM NIST):
InChIKey:JLYXXMFPNIAWKQ-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.7×101 Xiao et al. (2004) L 143)
2.7×101 Xiao et al. (2004) L 144)
2.8×101 7800 Sahsuvar et al. (2003) M
2.2×101 Altschuh et al. (1999) M
8.6 Mackay et al. (2006d) V
1.4×101 Ballschmiter and Wittlinger (1991) V
8.3 Suntio et al. (1988) V 9)
5.6×101 Suntio et al. (1988) C 255)
6.7×10−1 Ryan et al. (1988) C
7100 Kühne et al. (2005) Q
7800 Kühne et al. (2005) ?

References

  • Altschuh, J., Brüggemann, R., Santl, H., Eichinger, G., & Piringer, O. G.: Henry’s law constants for a diverse set of organic chemicals: Experimental determination and comparison of estimation methods, Chemosphere, 39, 1871–1887, doi:10.1016/S0045-6535(99)00082-X (1999).
  • Ballschmiter, K. & Wittlinger, R.: Interhemisphere exchange of hexachlorocyclohexanes, hexachlorobenzene, polychlorobiphenyls, and 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane in the lower troposphere, Environ. Sci. Technol., 25, 1103–1111, doi:10.1021/ES00018A014 (1991).
  • Kühne, R., Ebert, R.-U., & Schüürmann, G.: Prediction of the temperature dependency of Henry’s law constant from chemical structure, Environ. Sci. Technol., 39, 6705–6711, doi:10.1021/ES050527H (2005).
  • Mackay, D., Shiu, W. Y., Ma, K. C., & Lee, S. C.: Handbook of Physical-Chemical Properties and Environmental Fate for Organic Chemicals, vol. IV of Nitrogen and Sulfur Containing Compounds and Pesticides, CRC/Taylor & Francis Group (2006d).
  • Ryan, J. A., Bell, R. M., Davidson, J. M., & O’Connor, G. A.: Plant uptake of non-ionic organic chemicals from soils, Chemosphere, 17, 2299–2323, doi:10.1016/0045-6535(88)90142-7 (1988).
  • Sahsuvar, L., Helm, P. A., Jantunen, L. M., & Bidleman, T. F.: Henry’s law constants for α-, β-, and γ-hexachlorocyclohexanes (HCHs) as a function of temperature and revised estimates of gas exchange in Arctic regions, Atmos. Environ., 37, 983–992, doi:10.1016/S1352-2310(02)00936-6 (2003).
  • Suntio, L. R., Shiu, W. Y., Mackay, D., Seiber, J. N., & Glotfelty, D.: Critical review of Henry’s law constants for pesticides, Rev. Environ. Contam. Toxicol., 103, 1–59, doi:10.1007/978-1-4612-3850-8_1 (1988).
  • Xiao, H., Li, N., & Wania, F.: Compilation, evaluation, and selection of physical-chemical property data for α-, β-, and γ-hexachlorocyclohexane, J. Chem. Eng. Data, 49, 173–185, doi:10.1021/JE034214I (2004).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

9) Value at T = 293 K.
143) Literature-derived value.
144) Final adjusted value.
255) Value for T = 293... 298 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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