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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsOrganic species with oxygen (O)Peroxides (ROOH) and peroxy radicals (ROO) → methyl hydroperoxide

FORMULA:CH3OOH
TRIVIAL NAME: methyl peroxide
CAS RN:3031-73-0
STRUCTURE
(FROM NIST):
InChIKey:MEUKEBNAABNAEX-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
2.9 5200 Warneck and Williams (2012) L
3.0 5300 Sander et al. (2011) L
3.0 5300 Sander et al. (2006) L
3.1 5300 Staudinger and Roberts (2001) L
2.5 4400 Li et al. (2004) M
1.2×101 Sauer (1997) M 183)
3.1 5200 O’Sullivan et al. (1996) M
3.0 5300 Lind and Kok (1994) M 16)
9.0×10−1 Hilal et al. (2008) Q
6200 Kühne et al. (2005) Q
5200 Kühne et al. (2005) ?

References

  • Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
  • Kühne, R., Ebert, R.-U., & Schüürmann, G.: Prediction of the temperature dependency of Henry’s law constant from chemical structure, Environ. Sci. Technol., 39, 6705–6711, doi:10.1021/ES050527H (2005).
  • Li, S., Chen, Z., & Shi, F.: Determination of Henry’s Law constant for methyl hydroperoxide by long path FTIR, Prog. Nat. Sci., 14, 765–769, doi:10.1080/10020070412331344291 (2004).
  • Lind, J. A. & Kok, G. L.: Correction to “Henry’s law determinations for aqueous solutions of hydrogen peroxide, methylhydroperoxide, and peroxyacetic acid” by John A. Lind and Gregory L. Kok, J. Geophys. Res., 99D, 21 119, doi:10.1029/94jd01155 (1994).
  • O’Sullivan, D. W., Lee, M., Noone, B. C., & Heikes, B. G.: Henry’s law constant determinations for hydrogen peroxide, methyl hydroperoxide, hydroxymethyl hydroperoxide, ethyl hydroperoxide, and peroxyacetic acid, J. Phys. Chem., 100, 3241–3247, doi:10.1021/JP951168N (1996).
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL http://jpldataeval.jpl.nasa.gov (2006).
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL http://jpldataeval.jpl.nasa.gov (2011).
  • Sauer, F.: Bestimmung von H2O2 und organischen Peroxiden in Labor- und Feldmessungen mittels Umkehrphasen-Hochdruck-Flüssigkeitschromatographie und enzymatischer Nachsäulenderivatisierung, Ph.D. thesis, Johannes Gutenberg-Universität, Mainz, Germany (1997).
  • Staudinger, J. & Roberts, P. V.: A critical compilation of Henry’s law constant temperature dependence relations for organic compounds in dilute aqueous solutions, Chemosphere, 44, 561–576, doi:10.1016/S0045-6535(00)00505-1 (2001).
  • Warneck, P. & Williams, J.: The Atmospheric Chemist’s Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0 (2012).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

16) This value is a correction of the solubility published by Lind and Kok (1986).
183) Value at T = 278 K.

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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