Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Organic species with oxygen (O) → Polyols (R(OH)_n) → 2(R),3(S)-1,2,3,4-butanetetrol

FORMULA:	C₄H₁₀O₄
TRIVIAL NAME:	erythritol
CAS RN:	149-32-6
STRUCTURE (FROM NIST):
InChIKey:	UNXHWFMMPAWVPI-ZXZARUISSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
1.1×10¹⁰		Burkholder et al. (2019)	L
1.1×10¹⁰		Burkholder et al. (2015)	L
2.5×10⁹		Qin et al. (2021)	M	436)
1.1×10¹⁰	16000	Compernolle and Müller (2014b)	V
3.2×10⁴		Qin et al. (2021)	Q	437)
4.1×10⁸		Qin et al. (2021)	Q	438)
3.2×10⁴		HSDB (2015)	Q	100)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18, JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2015).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C., Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Percival, C. J., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2019).
Compernolle, S. & Müller, J.-F.: Henry’s law constants of polyols, Atmos. Chem. Phys., 14, 12 815–12 837, doi:10.5194/ACP-14-12815-2014 (2014b).
HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), URL https://www.nlm.nih.gov/toxnet/Accessing_HSDB_Content_from_PubChem.html (2015).
Qin, C., Gou, Y., Wang, Y., Mao, Y., Liao, H., Wang, Q., & Xie, M.: Gas–particle partitioning of polyol tracers at a suburban site in Nanjing, east China: increased partitioning to the particle phase, Atmos. Chem. Phys., 21, 12 141–12 153, doi:10.5194/ACP-21-12141-2021 (2021).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

100)	Calculated based on the method by Meylan and Howard (1991).
436)	Calculated based on atmospheric measurements.
437)	Calculated using EPI.
438)	Calculated using SPARC.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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