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Henry's Law Constants

www.henrys-law.org

Rolf Sander

NEW: Version 5.0.0 has been published in October 2023

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Inorganic species → Bromine (Br) → bromine chloride

FORMULA:BrCl
CAS RN:13863-41-7
STRUCTURE
(FROM NIST):
InChIKey:CODNYICXDISAEA-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) References Type Notes
[mol/(m3Pa)] [K]
9.7×10−3 5600 Burkholder et al. (2019) L
9.7×10−3 5600 Burkholder et al. (2015) L
9.7×10−3 5600 Sander et al. (2011) L
9.7×10−3 5600 Sander et al. (2006) L
< 6.2×10−2 Katrib et al. (2001) M 154)
1.5×10−2 Disselkamp et al. (1999) M 155)
9.3×10−3 5600 Bartlett and Margerum (1999) M
4.2×10−2 4000 Dubik et al. (1987) M 143)
1.1×10−2 T 156)
6.9×10−4 4000 Ordóñez et al. (2012) E
5.8×10−3 Frenzel et al. (1998) E

Data

The first column contains Henry's law solubility constant Hscp at the reference temperature of 298.15 K.
The second column contains the temperature dependence d ln Hs cp / d (1/T), also at the reference temperature.

References

  • Bartlett, W. P. & Margerum, D. W.: Temperature dependencies of the Henry’s law constant and the aqueous phase dissociation constant of bromine chloride, Environ. Sci. Technol., 33, 3410–3414, doi:10.1021/ES990300K (1999).
  • Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18, JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2015).
  • Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C., Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Percival, C. J., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2019).
  • Disselkamp, R. S., Chapman, E. G., Barchet, W. R., Colson, S. D., & Howd, C. D.: BrCl production in NaBr/NaCl/HNO3/O3 solutions representative of sea-salt aerosols in the marine boundary layer, Geophys. Res. Lett., 26, 2183–2186, doi:10.1029/1999GL900251 (1999).
  • Dubik, N. A., Titova, G. M., & Loshakova, E. I.: Partition coefficients of bromine and bromine chloride between air and natural brines, Issled. v Obl. Poluch. Magniya, Ioda, Broma i ikh Soed., M., pp. 53–57, (in Russian, see also Chem. Abstr., 109, 213154j) (1987).
  • Frenzel, A., Scheer, V., Sikorski, R., George, C., Behnke, W., & Zetzsch, C.: Heterogeneous interconversion reactions of BrNO2, ClNO2, Br2, and Cl2, J. Phys. Chem. A, 102, 1329–1337, doi:10.1021/JP973044B (1998).
  • Katrib, Y., Deiber, G., Schweitzer, F., Mirabel, P., & George, C.: Chemical transformation of bromine chloride at the air/water interface, J. Aerosol Sci., 32, 893–911, doi:10.1016/S0021-8502(00)00114-2 (2001).
  • Ordóñez, C., Lamarque, J.-F., Tilmes, S., Kinnison, D. E., Atlas, E. L., Blake, D. R., Sousa Santos, G., Brasseur, G., & Saiz-Lopez, A.: Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources, Atmos. Chem. Phys., 12, 1423–1447, doi:10.5194/ACP-12-1423-2012 (2012).
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL https://jpldataeval.jpl.nasa.gov (2006).
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2011).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

143) Dubik et al. (1987) measured the solubility in concentrated salt solutions (natural brines).
154) Value at T = 275 K.
155) Value at T = 290 K.
156) Calculated using data from Wagman et al. (1982) and the aqueous-phase equilibrium Cl2 + Br2 ↔ 2 BrCl from Wang et al. (1994).

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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