Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015

Henry's Law Constants → Organic species with oxygen (O) → Heterocycles with oxygen → tetrahydrofuran

FORMULA:	C₄H₈O
TRIVIAL NAME:	THF
CAS RN:	109-99-9
STRUCTURE (FROM NIST):
InChIKey:	WYURNTSHIVDZCO-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type
[mol/(m³Pa)]	[K]
2.2×10⁻¹		Signer et al. (1969)	M
1.4×10⁻¹	5700	Cabani et al. (1971b)	T
1.1×10⁻¹		Hilal et al. (2008)	Q
	4000	Kühne et al. (2005)	Q
	3200	Kühne et al. (2005)	?
1.4×10⁻¹		Abraham et al. (1990)	?

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Abraham, M. H., Whiting, G. S., Fuchs, R., & Chambers, E. J.: Thermodynamics of solute transfer from water to hexadecane, J. Chem. Soc. Perkin Trans. 2, pp. 291–300, doi:10.1039/P29900000291 (1990).
Cabani, S., Conti, G., & Lepori, L.: Thermodynamic study on aqueous dilute solutions of organic compounds. Part 2. – Cyclic ethers, Trans. Faraday Soc., 67, 1943–1950, doi:10.1039/TF9716701943 (1971b).
Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
Kühne, R., Ebert, R.-U., & Schüürmann, G.: Prediction of the temperature dependency of Henry’s law constant from chemical structure, Environ. Sci. Technol., 39, 6705–6711, doi:10.1021/ES050527H (2005).
Signer, R., Arm, H., & Daenicker, H.: Dampfdrücke, Dichten, thermodynamische Mischfunktionen und Brechungsindices der binären Systeme Wasser-Tetrahydrofuran und Wasser-Diäthyläther bei 25 ∘, Helv. Chim. Acta, 52, 2347–2351, doi:10.1002/HLCA.19690520816 (1969).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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