When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
FORMULA: | C3H8O2 |
TRIVIAL NAME:
|
methyl cellosolve
|
CAS RN: | 109-86-4 |
STRUCTURE
(FROM
NIST):
|
|
InChIKey: | XNWFRZJHXBZDAG-UHFFFAOYSA-N |
|
|
References |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
4.4 |
7500 |
Hiatt (2013) |
M |
|
2.2×10−4 |
-870 |
Ashworth et al. (1988) |
M |
103)
|
1.4×101 |
|
Johanson and Dynésius (1988) |
M |
19)
|
3.7×101 |
7300 |
Cabani et al. (1978) |
T |
|
2.1×101 |
|
Hilal et al. (2008) |
Q |
|
1.5×101 |
|
Nirmalakhandan et al. (1997) |
Q |
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Ashworth, R. A., Howe, G. B., Mullins, M. E., & Rogers, T. N.: Air-water partitioning coefficients of organics in dilute aqueous solutions, J. Hazard. Mater., 18, 25–36, doi:10.1016/0304-3894(88)85057-X (1988).
-
Cabani, S., Mollica, V., & Lepori, L.: Thermodynamic study of dilute aqueous solutions of organic compounds. Part 5. – Open-chain saturated bifunctional compounds, J. Chem. Soc. Faraday Trans. 1, 74, 2667–2671, doi:10.1039/F19787402667 (1978).
-
Hiatt, M. H.: Determination of Henry’s law constants using internal standards with benchmark values, J. Chem. Eng. Data, 58, 902–908, doi:10.1021/JE3010535 (2013).
-
Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
-
Johanson, G. & Dynésius, B.: Liquid/air partition coefficients of six commonly used glycol ethers, Br. J. Ind. Med., 45, 561–564, doi:10.1136/OEM.45.8.561 (1988).
-
Nirmalakhandan, N., Brennan, R. A., & Speece, R. E.: Predicting Henry’s law constant and the effect of temperature on Henry’s law constant, Wat. Res., 31, 1471–1481, doi:10.1016/S0043-1354(96)00395-8 (1997).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
19) |
Value at T = 310 K. |
103) |
The value is most probably taken from the report by Howe et al. (1987). |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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