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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 4.0) for water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015), doi:10.5194/acp-15-4399-2015


Henry's Law ConstantsHydrocarbons (C, H)Mononuclear aromatics → methylbenzene

FORMULA:C6H5CH3
TRIVIAL NAME: toluene
CAS RN:108-88-3
STRUCTURE
(FROM NIST):
InChIKey:YXFVVABEGXRONW-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) Reference Type Notes
[mol/(m3Pa)] [K]
1.5×10−3 4300 Staudinger and Roberts (2001) L
1.5×10−3 4000 Staudinger and Roberts (1996) L
1.5×10−3 Mackay and Shiu (1981) L
1.5×10−3 Kim and Kim (2014) M
2.1×10−3 4400 Hiatt (2013) M
2.8×10−3 Zhang et al. (2013) M
1.7×10−3 4200 Lee et al. (2013) M
1.5×10−3 Kish et al. (2013) M
1.3×10−3 2700 Lau et al. (2010) M 89)
1.5×10−3 4300 Sieg et al. (2009) M 121)
1.4×10−3 Helburn et al. (2008) M
1.5×10−3 Li et al. (2008) M
1.3×10−3 2100 Falabella and Teja (2008) M 89) 130)
1.4×10−3 Lodge and Danso (2007) M
Cheng et al. (2004) M 123)
1.4×10−3 2200 Lei et al. (2004) M 122)
Cheng et al. (2003) M 123)
1.4×10−3 Karl et al. (2003) M 31)
2.1×10−3 Bobadilla et al. (2003) M
1.7×10−3 4300 Bakierowska and Trzeszczyński (2003) M
2.0×10−3 Destaillats and Charles (2002) M
1.6×10−3 4100 Görgényi et al. (2002) M
1.7×10−3 3600 Bierwagen and Keller (2001) M
1.0×10−3 Ayuttaya et al. (2001) M 131)
1.7×10−4 Ayuttaya et al. (2001) M 132)
7.8×10−4 Ayuttaya et al. (2001) M 133)
2.3×10−3 Ayuttaya et al. (2001) M 134)
1.5×10−3 David et al. (2000) M 126)
1.6×10−3 Miller and Stuart (2000) M 126)
1.9×10−3 4000 Vane and Giroux (2000) M
1.5×10−3 4700 Dewulf et al. (1999) M
1.7×10−3 Altschuh et al. (1999) M
1.5×10−3 Ryu and Park (1999) M
1.6×10−3 Dohnal and Hovorka (1999) M
1.5×10−3 Allen et al. (1998) M
2.1×10−3 Peng and Wan (1998) M
1.2×10−3 3600 Peng and Wan (1998) M 127)
2.0×10−3 de Wolf and Lieder (1998) M 31)
1.7×10−3 3700 Peng and Wan (1997) M
1.7×10−3 2800 Kondoh and Nakajima (1997) M
1.3×10−3 3900 Park et al. (1997) M
1.4×10−3 4100 Turner et al. (1996) M
1.5×10−3 Ramachandran et al. (1996) M
1.8×10−3 4400 Dewulf et al. (1995) M
1.6×10−3 Nielsen et al. (1994) M
1.5×10−3 3400 Robbins et al. (1993) M
1.3×10−3 Hoff et al. (1993) M
1.5×10−3 2500 Ettre et al. (1993) M 89)
1.4×10−3 Hansen et al. (1993) M 128)
1.5×10−3 4500 Perlinger et al. (1993) M
1.6×10−3 Li and Carr (1993) M
1.6×10−3 Li et al. (1993) M
1.5×10−3 Zhang and Pawliszyn (1993) M
1.6×10−3 2500 Kolb et al. (1992) M 102)
1.5×10−3 Anderson (1992) M 126)
1.4×10−3 5000 Bissonette et al. (1990) M
1.5×10−3 6500 Lamarche and Droste (1989) M 135)
1.5×10−3 3000 Ashworth et al. (1988) M 103)
1.6×10−3 Keeley et al. (1988) M
1.7×10−3 Yurteri et al. (1987) M 9)
1.2×10−3 5400 Schoene and Steinhanses (1985) M
1.5×10−3 Garbarini and Lion (1985) M
1.5×10−3 4200 Sanemasa et al. (1982) M
1.5×10−3 3800 Leighton and Calo (1981) M
1.6×10−3 4100 Sanemasa et al. (1981) M
1.5×10−3 4900 Ervin et al. (1980) M
1.7×10−3 Warner et al. (1980) M
1.5×10−3 Mackay et al. (1979) M
8.6×10−4 Sato and Nakajima (1979a) M 19)
1.5×10−3 4700 Tsibul’skii et al. (1979) M
1.9×10−3 Vitenberg et al. (1975) M
1.6×10−3 5000 Brown and Wasik (1974) M
2.0×10−3 4900 Hartkopf and Karger (1973) M
1.7×10−3 5900 Wasik and Tsang (1970) M
1.5×10−3 Mackay et al. (2006a) V
1.5×10−3 Shiu and Ma (2000) V
1.5×10−3 Park et al. (1997) V
1.5×10−3 Mackay et al. (1992a) V
1.3×10−3 Hwang et al. (1992) V
1.7×10−3 Eastcott et al. (1988) V
1.5×10−3 4400 Abraham (1984) V
1.9×10−3 4200 Ben-Naim and Wilf (1980) V
1.5×10−3 Warner et al. (1980) V
1.5×10−3 Hine and Mookerjee (1975) V
1.5×10−3 Mackay and Leinonen (1975) V
1.8×10−3 4300 Andon et al. (1954) V 129)
1.8×10−3 Bohon and Claussen (1951) V
1.5×10−3 Mackay et al. (1979) T
4400 Gill et al. (1976) T 100)
1.9×10−3 4300 Shaw (1989) X 3)
1.5×10−3 1900 Goldstein (1982) X 116)
1.5×10−3 McAuliffe (1971) X 136)
1.5×10−3 Sieg et al. (2008) C
1.5×10−3 Schüürmann (2000) C 7)
1.7×10−3 Smith et al. (1993) C 9)
1.4×10−3 Ryan et al. (1988) C
1.7×10−3 Shen (1982) C
1.5×10−3 Hilal et al. (2008) Q
4300 Kühne et al. (2005) Q
1.6×10−3 Nirmalakhandan and Speece (1988a) Q
1.2×10−3 Arbuckle (1983) Q
4200 Kühne et al. (2005) ?
1.5×10−3 Yaws and Yang (1992) ? 92)
1.5×10−3 Abraham et al. (1990) ?
1.9×10−3 Mackay and Yeun (1983) ?

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Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2015) for further details.

Notes

3) Value given here as quoted by Fogg and Sangster (2003).
7) Several references are given in the list of Henry's law constants but not assigned to specific species.
9) Value at T = 293 K.
19) Value at T = 310 K.
31) Value at T = 295 K.
89) Measured at high temperature and extrapolated to T = 298.15 K.
92) Yaws and Yang (1992) give several references for the Henry's law constants but don't assign them to specific species.
100) Calculated from the solvation enthalpy, using the van 't Hoff equation.
102) Extrapolated from data measured between 40 °C and 80 °C.
103) The value is most probably taken from the report by Howe et al. (1987).
116) Value given here as quoted by Staudinger and Roberts (1996).
121) Sieg et al. (2009) also provide data for supercooled water. Here, only data above 0 °C were used to calculate the temperature dependence.
122) Extrapolated from data above 298 K.
123) It was found that Hs changes with the concentration of the solution.
126) Value at T = 296 K.
127) Solubility in sea water.
128) Value at T = 302 K.
129) Calculated using Gh and Hh from Table 2 in Andon et al. (1954). Note that the thermodynamic functions in that table are not based on their α in Table 1. Instead, the expression exp(−Gh/(RT)) yields the Henry's law constant Hsxp in the unit 1/atm.
130) Values for salt solutions are also available from this reference.
131) Value obtained by applying the EPICS method, see Ayuttaya et al. (2001) for details.
132) Value obtained by applying the static cell (linear form) method, see Ayuttaya et al. (2001) for details.
133) Value obtained by applying the direct phase concentration ratio method, see Ayuttaya et al. (2001) for details.
134) Value obtained by applying the static cell (non-linear form) method, see Ayuttaya et al. (2001) for details.
135) The temperature dependence is recalculated using the data in Table 4 of Lamarche and Droste (1989) and not taken from their Table 5.
136) Value given here as quoted by Dewulf et al. (1995).

The numbers of the notes are the same as in Sander (2015). References cited in the notes can be found here.

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