Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Organic species with other elements → Silicon (Si) → octamethyltrisiloxane

FORMULA:	C₈H₂₄O₂Si₃
TRIVIAL NAME:	L3
CAS RN:	107-51-7
STRUCTURE (FROM NIST):
InChIKey:	CXQXSVUQTKDNFP-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
3.4×10⁻⁷		Xu and Kropscott (2014)	M
3.3×10⁻⁶		Kochetkov et al. (2001)	M	332) 404)
2.7×10⁻⁶		Kochetkov et al. (2001)	M	333) 404)
2.8×10⁻⁷		Xu and Kropscott (2014)	V
2.8×10⁻⁷		Kochetkov et al. (2001)	V
1.2×10⁻⁶		Mazzoni et al. (1997)	V
1.3×10⁻⁵		Keshavarz et al. (2022)	Q
2.5×10⁻⁵		Duchowicz et al. (2020)	Q
3.0×10⁻⁶		Duchowicz et al. (2020)	?	21) 186)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Duchowicz, P. R., Aranda, J. F., Bacelo, D. E., & Fioressi, S. E.: QSPR study of the Henry’s law constant for heterogeneous compounds, Chem. Eng. Res. Des., 154, 115–121, doi:10.1016/J.CHERD.2019.12.009 (2020).
Keshavarz, M. H., Rezaei, M., & Hosseini, S. H.: A simple approach for prediction of Henry’s law constant of pesticides, solvents, aromatic hydrocarbons, and persistent pollutants without using complex computer codes and descriptors, Process Saf. Environ. Prot., 162, 867–877, doi:10.1016/J.PSEP.2022.04.045 (2022).
Kochetkov, A., Smith, J. S., Ravikrishna, R., Valsaraj, K. T., & Thibodeaux, L. J.: Air–water partition constants for volatile methyl siloxanes, Environ. Toxicol. Chem., 20, 2184–2188, doi:10.1002/ETC.5620201008 (2001).
Mazzoni, S. M., Roy, S., & Grigoras, S.: Eco-relevant properties of selected organosilicon materials, in: The Handbook of Environmental Chemistry, Vol. 3. Part H. Organosilicon Materials, edited by Chandra, G., pp. 53–81, Springer Verlag, Berlin, doi:10.1007/978-3-540-68331-5 (1997).
Xu, S. & Kropscott, B.: Evaluation of the three-phase equilibrium method for measuring temperature dependence of internally consistent partition coefficients (K_OW, K_OA, and K_AW) for volatile methylsiloxanes and trimethylsilanol, Environ. Toxicol. Chem., 33, 2702–2710, doi:10.1002/ETC.2754 (2014).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

21)	Several references are given in the list of Henry's law constants but not assigned to specific species.
186)	Experimental value, extracted from HENRYWIN.
332)	Value obtained by applying a modified batch air-stripping method, otherwise called the vapor entry loop (VEL) method; see Kochetkov et al. (2001) for details.
333)	Value obtained by applying the static head space (HS) method; see Kochetkov et al. (2001) for details.
404)	Value at T = 300 K.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

* * *

Search Henry's Law Database

* * *

Convert Henry's Law Constants

	Convert:

Henry's Law Constants

www.henrys-law.org

Rolf Sander

Home