When referring to the compilation of Henry's Law Constants, please cite
this publication:
R. Sander: Compilation of Henry's law constants (version 4.0) for
water as solvent, Atmos. Chem. Phys., 15, 4399-4981 (2015),
doi:10.5194/acp-15-4399-2015
|
FORMULA: | HO(CH2)2OH |
TRIVIAL NAME:
|
ethylene glycol
|
CAS RN: | 107-21-1 |
STRUCTURE
(FROM
NIST):
|
|
InChIKey: | LYCAIKOWRPUZTN-UHFFFAOYSA-N |
|
|
References |
Type |
Notes |
[mol/(m3Pa)] |
[K] |
|
|
|
4.0×103 |
|
Bone et al. (1983) |
M |
9)
|
1.6×102 |
|
Butler and Ramchandani (1935) |
M |
173)
|
4.7 |
|
HSDB (2015) |
V |
|
6.5×103 |
8800 |
Compernolle and Müller (2014b) |
V |
|
5.0×103 |
|
Hwang et al. (1992) |
V |
|
7.2×102 |
|
Hilal et al. (2008) |
Q |
|
Data
The first column contains Henry's law solubility constant
at the reference temperature of 298.15 K.
The second column contains the temperature dependence
, also at the
reference temperature.
References
-
Bone, R., Cullis, P., & Wolfenden, R.: Solvent effects on equilibria of addition of nucleophiles to acetaldehyde and the hydrophilic character of diols, J. Am. Chem. Soc., 105, 1339–1343, doi:10.1021/JA00343A044 (1983).
-
Butler, J. A. V. & Ramchandani, C. N.: The solubility of non-electrolytes. Part II. The influence of the polar group on the free energy of hydration of aliphatic compounds, J. Chem. Soc., pp. 952–955, doi:10.1039/JR9350000952 (1935).
-
Compernolle, S. & Müller, J.-F.: Henry’s law constants of polyols, Atmos. Chem. Phys., 14, 12 815–12 837, doi:10.5194/acp-14-12815-2014 (2014b).
-
Hilal, S. H., Ayyampalayam, S. N., & Carreira, L. A.: Air-liquid partition coefficient for a diverse set of organic compounds: Henry’s law constant in water and hexadecane, Environ. Sci. Technol., 42, 9231–9236, doi:10.1021/ES8005783 (2008).
-
HSDB: Hazardous Substances Data Bank, TOXicology data NETwork (TOXNET), National Library of Medicine (US), URL http://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm (2015).
-
Hwang, Y.-L., Olson, J. D., & Keller, II, G. E.: Steam stripping for removal of organic pollutants from water. 2. Vapor-liquid equilibrium data, Ind. Eng. Chem. Res., 31, 1759–1768, doi:10.1021/IE00007A022 (1992).
Type
Table entries are sorted according to reliability of the data, listing
the most reliable type first: L) literature review, M) measured, V)
VP/AS = vapor pressure/aqueous solubility, R) recalculation, T)
thermodynamical calculation, X) original paper not available, C)
citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1
of Sander (2015) for further details.
Notes
9) |
Value at T = 293 K. |
173) |
Saxena and Hildemann (1996) say that this value is unreliable. |
The numbers of the notes are the same as
in Sander (2015). References cited in the notes can be
found here.
|
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