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Henry's Law Constants

www.henrys-law.org

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Inorganic species → Nitrogen (N) → nitrogen dioxide

FORMULA:NO2
CAS RN:10102-44-0
STRUCTURE
(FROM NIST):
InChIKey:JCXJVPUVTGWSNB-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) References Type Notes
[mol/(m3Pa)] [K]
1.2×10−4 2400 Burkholder et al. (2019) L
1.2×10−4 2400 Burkholder et al. (2015) L
9.9×10−5 Warneck and Williams (2012) L
1.2×10−4 2400 Sander et al. (2011) L
1.4×10−4 Sander et al. (2006) L
1.2×10−4 Schwartz and White (1981) L
1.2×10−4 2400 Cheung et al. (2000) M
6.9×10−5 Lee and Schwartz (1981) M 88)
2.3×10−4 Komiyama and Inoue (1980) M 81)
1.2×10−4 2500 Chameides (1984) T
3.4×10−4 1800 Berdnikov and Bazhin (1970) T 48)
9.9×10−5 Pandis and Seinfeld (1989) ? 89)
9.9×10−5 Seinfeld (1986) ? 21)
4.0×10−4 Andrew and Hanson (1961) ?

Data

The first column contains Henry's law solubility constant Hscp at the reference temperature of 298.15 K.
The second column contains the temperature dependence d ln Hs cp / d (1/T), also at the reference temperature.

References

  • Andrew, S. P. S. & Hanson, D.: The dynamics of nitrous gas absorption, Chem. Eng. Sci., 14, 105–113, doi:10.1016/0009-2509(61)85060-4 (1961).
  • Berdnikov, V. M. & Bazhin, N. M.: Oxidation-reduction potentials of certain inorganic radicals in aqueous solutions, Russ. J. Phys. Chem., 44, 395–398 (1970).
  • Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18, JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2015).
  • Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C., Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Percival, C. J., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2019).
  • Chameides, W. L.: The photochemistry of a remote marine stratiform cloud, J. Geophys. Res., 89, 4739–4755, doi:10.1029/JD089ID03P04739 (1984).
  • Cheung, J. L., Li, Y. Q., Boniface, J., Shi, Q., Davidovits, P., Worsnop, D. R., Jayne, J. T., & Kolb, C. E.: Heterogeneous interactions of NO2 with aqueous surfaces, J. Phys. Chem. A, 104, 2655–2662, doi:10.1021/JP992929F (2000).
  • Komiyama, H. & Inoue, H.: Absorption of nitrogen oxides into water, Chem. Eng. Sci., 35, 154–161, doi:10.1016/0009-2509(80)80082-0 (1980).
  • Lee, Y.-N. & Schwartz, S. E.: Reaction kinetics of nitrogen dioxide with liquid water at low partial pressure, J. Phys. Chem., 85, 840–848, doi:10.1021/J150607A022 (1981).
  • Pandis, S. N. & Seinfeld, J. H.: Sensitivity analysis of a chemical mechanism for aqueous-phase atmospheric chemistry, J. Geophys. Res., 94, 1105–1126, doi:10.1029/JD094ID01P01105 (1989).
  • Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL https://jpldataeval.jpl.nasa.gov (2006).
  • Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2011).
  • Schwartz, S. E. & White, W. H.: Solubility equilibria of the nitrogen oxides and oxyacids in dilute aqueous solution, in: Advances in Environmental Science and Engineering, edited by Pfafflin, J. R. & Ziegler, E. N., vol. 4, pp. 1–45, Gordon and Breach Science Publishers, NY (1981).
  • Seinfeld, J. H.: Atmospheric Chemistry and Physics of Air Pollution, Wiley-Interscience Publication, NY, ISBN 0471828572 (1986).
  • Warneck, P. & Williams, J.: The Atmospheric Chemist’s Companion: Numerical Data for Use in the Atmospheric Sciences, Springer Verlag, doi:10.1007/978-94-007-2275-0 (2012).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

21) Several references are given in the list of Henry's law constants but not assigned to specific species.
48) Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit.
81) Value at T = 288 K.
88) Value at T = 295 K.
89) Pandis and Seinfeld (1989) refer to Schwartz (1984) as the source, but the quoted value cannot be found there.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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