Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Inorganic species → Bromine (Br) → bromine atom

FORMULA:	Br
CAS RN:	10097-32-2
STRUCTURE (FROM NIST):
InChIKey:	WKBOTKDWSSQWDR-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
1.2×10⁻²		Mozurkewich (1986)	T	120)
3.4×10⁻⁴	1800	Berdnikov and Bazhin (1970)	T	48)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Berdnikov, V. M. & Bazhin, N. M.: Oxidation-reduction potentials of certain inorganic radicals in aqueous solutions, Russ. J. Phys. Chem., 44, 395–398 (1970).
Mozurkewich, M.: Comment on “Possible role of NO₃ in the nighttime chemistry of a cloud” by William L. Chameides, J. Geophys. Res., 91, 14 569–14 570, doi:10.1029/JD091ID13P14569 (1986).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

48)	Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit.
120)	Calculated from the free energy of solution by Schwarz and Dodson (1984).

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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