Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Inorganic species → Chlorine (Cl) → chlorine dioxide

FORMULA:	ClO₂
CAS RN:	10049-04-4
STRUCTURE (FROM NIST):
InChIKey:	OSVXSBDYLRYLIG-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
1.0×10⁻²	3500	Burkholder et al. (2019)	L
1.0×10⁻²	3500	Burkholder et al. (2015)	L
1.0×10⁻²	3500	Sander et al. (2011)	L
1.0×10⁻²	3500	Sander et al. (2006)	L
1.0×10⁻²	3300	Young (1983)	L	1)
1.0×10⁻²	3300	Wilhelm et al. (1977)	L
1.0×10⁻²	3200	Kepinski and Trzeszczynski (1964)	M
1.1×10⁻²	3100	Ishi (1958)	M
1.0×10⁻²		Taube and Dodgen (1949)	M
6.6×10⁻³	1200	Bigorgne (1947)	M
9.7×10⁻³	3600	Holst (1944)	M
		Haller and Northgraves (1955)	C	140)
1.1×10⁻²	3100	Mavu (2011)	?
9.7×10⁻³		Morrow et al. (2006)	?
1.0×10⁻²	3300	Yaws et al. (1999)	?	21)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Bigorgne, M.: Formation de chlorites à partir de peroxyde de chlore et de métaux, C. R. Hebd. Séances Acad. Sci., 225, 527–529 (1947).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18, JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2015).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C., Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Percival, C. J., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2019).
Haller, J. F. & Northgraves, W. W.: Chlorine dioxide and safety, TAPPI, 38, 199–202 (1955).
Holst, G.: Die Grundlagen einer technischen Methode zur Darstellung von Chlordioxyd, Svensk Papperstidn., 47, 537–546 (1944).
Ishi, G.: Solubility of chlorine dioxide, Chem. Eng. (Japan), 22, 153–154, doi:10.1252/KAKORONBUNSHU1953.22.153 (1958).
Kepinski, J. & Trzeszczynski, J.: Absorption equilibria of chlorine dioxide. Solubility in water, carbon tetrachloride, sulphuric and acetic acid solutions, Rocz. Chem., 38, 201–211 (1964).
Mavu, D. M.: Pharmaceutical formulation and in-vitro testing of Dioxy MP 14 (stabilised chlorine dioxide) against mycobacteria tuberculosis, Master’s thesis, University of the Western Cape, South Africa, URL https://etd.uwc.ac.za/xmlui/handle/11394/5372 (2011).
Morrow, M., McMahon, T., Leighton, T., Shamim, N., Angle, G., Chen, J., Carlisle, S., Isbell, D., Slotnick, J., Mitchell, E., Henson, W., Koch, E., & Knorr, M.: Reregistration eligibility decision (RED) for chlorine dioxide and sodium chlorite (case 4023), Tech. Rep. EPA 738-R-06-007, United States Environmental Protection Agency, URL https://www3.epa.gov/pesticides/chem_search/reg_actions/reregistration/red_PC-020503_3-Aug-06.pdf (2006).
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL https://jpldataeval.jpl.nasa.gov (2006).
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2011).
Taube, H. & Dodgen, H.: Applications of radioactive chlorine to the study of the mechanisms of reactions involving changes in the oxidation state of chlorine, J. Am. Chem. Soc., 71, 3330–3336, doi:10.1021/JA01178A016 (1949).
Wilhelm, E., Battino, R., & Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219–262, doi:10.1021/CR60306A003 (1977).
Yaws, C. L., Hopper, J. R., Wang, X., Rathinsamy, A. K., & Pike, R. W.: Calculating solubility & Henry’s law constants for gases in water, Chem. Eng., pp. 102–105 (1999).
Young, C. L.: IUPAC Solubility Data Series, Volume 12, Sulfur Dioxide, Chlorine, Fluorine and Chlorine Oxides, Pergamon Press, Oxford, doi:10.1016/C2013-0-03419-6 (1983).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

1)	A detailed temperature dependence with more than one parameter is available in the original publication. Here, only the temperature dependence at 298.15 K according to the van 't Hoff equation is presented.
21)	Several references are given in the list of Henry's law constants but not assigned to specific species.
140)	Even though Haller and Northgraves (1955) have been cited several times as the source of the ClO₂ solubility data, they did not perform any measurements. They took the data from the 1952 edition of the Kirk-Othmer Encyclopedia of Chemical Technology which apparently reproduced data from Holst (1944).

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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