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Henry's Law Constants

www.henrys-law.org

Rolf Sander

NEW: Version 5.0.0 has been published in October 2023

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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Henry's Law Constants

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When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.


Henry's Law ConstantsInorganic speciesIodine (I) → hydrogen iodide

FORMULA:HI
CAS RN:10034-85-2
STRUCTURE
(FROM NIST):
InChIKey:XMBWDFGMSWQBCA-UHFFFAOYSA-N

Hscp d ln Hs cp / d (1/T) References Type Notes
[mol/(m3Pa)] [K]
Brimblecombe and Clegg (1989) T 159)
Wagman et al. (1982) T 160)
2.5×10−1 9800 Ordóñez et al. (2012) E
Vogt et al. (1999) E 99)
Brimblecombe and Clegg (1988) W 105)

Data

The first column contains Henry's law solubility constant Hscp at the reference temperature of 298.15 K.
The second column contains the temperature dependence d ln Hs cp / d (1/T), also at the reference temperature.

References

  • Brimblecombe, P. & Clegg, S. L.: The solubility and behaviour of acid gases in the marine aerosol, J. Atmos. Chem., 7, 1–18, doi:10.1007/BF00048251 (1988).
  • Brimblecombe, P. & Clegg, S. L.: Erratum, J. Atmos. Chem., 8, 95, doi:10.1007/BF00053818 (1989).
  • Ordóñez, C., Lamarque, J.-F., Tilmes, S., Kinnison, D. E., Atlas, E. L., Blake, D. R., Sousa Santos, G., Brasseur, G., & Saiz-Lopez, A.: Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources, Atmos. Chem. Phys., 12, 1423–1447, doi:10.5194/ACP-12-1423-2012 (2012).
  • Vogt, R., Sander, R., von Glasow, R., & Crutzen, P. J.: Iodine chemistry and its role in halogen activation and ozone loss in the marine boundary layer: A model study, J. Atmos. Chem., 32, 375–395, doi:10.1023/A:1006179901037 (1999).
  • Wagman, D. D., Evans, W. H., Parker, V. B., Schumm, R. H., Halow, I., Bailey, S. M., Churney, K. L., & Nuttall, R. L.: The NBS tables of chemical thermodynamic properties; Selected values for inorganic and C1 and C2 organic substances in SI units, J. Phys. Chem. Ref. Data, 11, suppl. 2, URL https://srd.nist.gov/JPCRD/jpcrdS2Vol11.pdf (1982).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

99) Fast, irreversible hydrolysis is assumed, which is equivalent to an infinite effective Henry's law constant.
105) The value is incorrect. See erratum by Brimblecombe and Clegg (1989).
159) Hs′ = 2.5×1010×exp(9800 K (1/T−1/T)) mol2/(m6 Pa)
160) Hs′ = 2.1×1010×exp(9800 K (1/T−1/T)) mol2/(m6 Pa)

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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