Henry's Law Constants

Rolf Sander

Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

Errata

Contact, Imprint, Acknowledgements

When referring to the compilation of Henry's Law Constants, please cite this publication:

R. Sander: Compilation of Henry's law constants (version 5.0.0) for water as solvent, Atmos. Chem. Phys., 23, 10901-12440 (2023), doi:10.5194/acp-23-10901-2023

The publication from 2023 replaces that from 2015, which is now obsolete. Please do not cite the old paper anymore.

Henry's Law Constants → Inorganic species → Oxygen (O) → ozone

FORMULA:	O₃
CAS RN:	10028-15-6
STRUCTURE (FROM NIST):
InChIKey:	CBENFWSGALASAD-UHFFFAOYSA-N

$H_{s}^{cp}$	$d ln H_{s}^{cp} / d (1/ T)$	References	Type	Notes
[mol/(m³Pa)]	[K]
1.0×10⁻⁴	2800	Burkholder et al. (2019)	L
1.0×10⁻⁴	2800	Burkholder et al. (2015)	L
		Clever et al. (2014)	L	25)
1.0×10⁻⁴	2800	Sander et al. (2011)	L
1.0×10⁻⁴	2800	Sander et al. (2006)	L
7.6×10⁻⁵	3700	Biń (2005)	L
1.1×10⁻⁴	2400	Warneck (2003)	L
		Battino (1981)	L	26)
1.3×10⁻⁴	2000	Wilhelm et al. (1977)	L
1.1×10⁻⁴		Levanov et al. (2008)	M	12)
1.1×10⁻⁴	2300	Gershenzon et al. (2001)	M
9.9×10⁻⁵	2600	Rischbieter et al. (2000)	M
9.2×10⁻⁵	2600	Andreozzi et al. (1996)	M
1.2×10⁻⁴	1400	Sotelo et al. (1989)	M
1.1×10⁻⁴	2300	Kosak-Channing and Helz (1983)	M
1.7×10⁻⁴		Gurol and Singer (1982)	M	12)
		Roth and Sullivan (1981)	M	27)
1.2×10⁻⁴	1900	Stumm (1958)	M
9.9×10⁻⁵	2600	Kilpatrick et al. (1956)	M
1.3×10⁻⁴	2000	Briner and Perrottet (1939)	M
2.0×10⁻⁴		Fischer and Tropsch (1917)	M
8.0×10⁻⁵	2900	Luther (1905)	M
1.2×10⁻⁴	4100	Mailfert (1894)	M
1.2×10⁻⁴		Schöne (1873)	M	28)
1.1×10⁻⁴	2600	Chameides (1984)	T
1.2×10⁻⁴		Perry and Chilton (1973)	X	29)
1.2×10⁻⁴		Hayer et al. (2022)	Q	20)
		Lide and Frederikse (1995)	?	30)
9.3×10⁻⁵	2500	Seinfeld (1986)	?	21)
9.3×10⁻⁵	2500	Hoffmann and Jacob (1984)	?	21)

Data

The first column contains Henry's law solubility constant

H_{s}^{cp}

at the reference temperature of 298.15 K.
The second column contains the temperature dependence

d ln H_{s}^{cp} / d
(1/ T)

, also at the reference temperature.

References

Andreozzi, R., Caprio, V., Ermellino, I., Insola, A., & Tufano, V.: Ozone solubility in phosphate-buffered aqueous solutions: effect of temperature, tert-butyl alcohol, and pH, Ind. Eng. Chem. Res., 35, 1467–1471, doi:10.1021/IE940778R (1996).
Battino, R.: IUPAC Solubility Data Series, Volume 7, Oxygen and Ozone, Pergamon Press, Oxford, doi:10.1016/C2013-0-03145-3 (1981).
Biń, A. K.: Ozone solubility in liquids, Ozone: Sci. Eng., 28, 67–75, doi:10.1080/01919510600558635 (2005).
Briner, E. & Perrottet, E.: Détermination des solubilités de l’ozone dans l’eau et dans une solution aqueuse de chlorure de sodium; calcul des solubilités de l’ozone atmosphérique dans les eaux, Helv. Chim. Acta, 22, 397–404, doi:10.1002/HLCA.19390220151 (1939).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18, JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2015).
Burkholder, J. B., Sander, S. P., Abbatt, J., Barker, J. R., Cappa, C., Crounse, J. D., Dibble, T. S., Huie, R. E., Kolb, C. E., Kurylo, M. J., Orkin, V. L., Percival, C. J., Wilmouth, D. M., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 19, JPL Publication 19-5, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2019).
Chameides, W. L.: The photochemistry of a remote marine stratiform cloud, J. Geophys. Res., 89, 4739–4755, doi:10.1029/JD089ID03P04739 (1984).
Clever, H. L., Battino, R., Miyamoto, H., Yampolski, Y., & Young, C. L.: IUPAC-NIST solubility data series. 103. Oxygen and ozone in water, aqueous solutions, and organic liquids (supplement to solubility data series volume 7), J. Phys. Chem. Ref. Data, 43, 033 102, doi:10.1063/1.4883876 (2014).
Fischer, F. & Tropsch, H.: Notiz über Farbe und Oxydationswert einiger Ozonlösungen, Ber. Dtsch. Chem. Ges., 50, 765–767, doi:10.1002/CBER.191705001124 (1917).
Gershenzon, M., Davidovits, P., Jayne, J. T., Kolb, C. E., & Worsnop, D. R.: Simultaneous uptake of DMS and ozone on water, J. Phys. Chem. A, 105, 7031–7036, doi:10.1021/JP010696Y (2001).
Gurol, M. D. & Singer, P. C.: Kinetics of ozone decomposition: a dynamic approach, Environ. Sci. Technol., 16, 377–383, doi:10.1021/ES00101A003 (1982).
Hayer, N., Jirasek, F., & Hasse, H.: Prediction of Henry’s law constants by matrix completion, AIChE J., 68, e17 753, doi:10.1002/AIC.17753 (2022).
Hoffmann, M. R. & Jacob, D. J.: Kinetics and mechanisms of the catalytic oxidation of dissolved sulfur dioxide in aqueous solution: An application to nighttime fog water chemistry, in: SO₂, NO and NO₂ Oxidation Mechanisms: Atmospheric Considerations, edited by Calvert, J. G., pp. 101–172, Butterworth Publishers, Boston, MA, ISBN 0250405687 (1984).
Kilpatrick, M. L., Herrick, C. C., & Kilpatrick, M.: The decomposition of ozone in aqueous solution, J. Am. Chem. Soc., 78, 1784–1789, doi:10.1021/JA01590A003 (1956).
Kosak-Channing, L. F. & Helz, G. R.: Solubility of ozone in aqueous solutions of 0–0.6 M ionic strength at 5–30∘C, Environ. Sci. Technol., 17, 145–149, doi:10.1021/ES00109A005 (1983).
Levanov, A. V., Kuskov, I. V., Antipenko, E. E., & Lunin, V. V.: The solubility of ozone in aqueous solutions of sulfuric, phosphoric, and perchloric acids, Russ. J. Phys. Chem. A, 82, 1126–1131 (2008).
Lide, D. R. & Frederikse, H. P. R.: CRC Handbook of Chemistry and Physics, 76th Edition, CRC Press, Inc., Boca Raton, FL, ISBN 0849304768 (1995).
Luther, R.: Zur Kenntnis des Ozons, Z. Elektrochem., 11, 832–835, doi:10.1002/BBPC.19050114704 (1905).
Mailfert, M.: Sur la solubilité de l’ozone, C. R. Hebd. Séances Acad. Sci., 119, 951–953 (1894).
Perry, R. H. & Chilton, C. H.: Chemical Engineers’ Handbook, 5th edition, McGraw-Hill, Inc., ISBN 0070855471 (1973).
Rischbieter, E., Stein, H., & Schumpe, A.: Ozone solubilities in water and aqueous salt solutions, J. Chem. Eng. Data, 45, 338–340, doi:10.1021/JE990263C (2000).
Roth, J. A. & Sullivan, D. E.: Solubility of ozone in water, Ind. Eng. Chem. Fund., 20, 137–140 (1981).
Sander, S. P., Friedl, R. R., Golden, D. M., Kurylo, M. J., Moortgat, G. K., Keller-Rudek, H., Wine, P. H., Ravishankara, A. R., Kolb, C. E., Molina, M. J., Finlayson-Pitts, B. J., Huie, R. E., & Orkin, V. L.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, CA, URL https://jpldataeval.jpl.nasa.gov (2006).
Sander, S. P., Abbatt, J., Barker, J. R., Burkholder, J. B., Friedl, R. R., Golden, D. M., Huie, R. E., Kolb, C. E., Kurylo, M. J., Moortgat, G. K., Orkin, V. L., & Wine, P. H.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 17, JPL Publication 10-6, Jet Propulsion Laboratory, Pasadena, URL https://jpldataeval.jpl.nasa.gov (2011).
Schöne, E.: Ueber das Verhalten von Ozon und Wasser zu einander, Ber. Dtsch. Chem. Ges., 6, 1224–1229, doi:10.1002/CBER.187300602111 (1873).
Seinfeld, J. H.: Atmospheric Chemistry and Physics of Air Pollution, Wiley-Interscience Publication, NY, ISBN 0471828572 (1986).
Sotelo, J. L., Beltrán, F. J., Benitez, F. J., & Beltrán-Heredia, J.: Henry’s law constant for the ozone-water system, Wat. Res., 23, 1239–1246, doi:10.1016/0043-1354(89)90186-3 (1989).
Stumm, W.: Ozone as a disinfectant for water and sewage, J. Boston Soc. Civil Eng., 45, 68–79 (1958).
Warneck, P.: The solubility of ozone in water, in: Chemicals in the Atmosphere: Solubility, Sources and Reactivity, edited by Fogg, P. & Sangster, J., pp. 225–228, John Wiley & Sons, Inc., ISBN 978-0-471-98651-5 (2003).
Wilhelm, E., Battino, R., & Wilcock, R. J.: Low-pressure solubility of gases in liquid water, Chem. Rev., 77, 219–262, doi:10.1021/CR60306A003 (1977).

Type

Table entries are sorted according to reliability of the data, listing the most reliable type first: L) literature review, M) measured, V) VP/AS = vapor pressure/aqueous solubility, R) recalculation, T) thermodynamical calculation, X) original paper not available, C) citation, Q) QSPR, E) estimate, ?) unknown, W) wrong. See Section 3.1 of Sander (2023) for further details.

Notes

12)	Value at T = 293 K.
20)	Calculated using machine learning matrix completion methods (MCMs).
21)	Several references are given in the list of Henry's law constants but not assigned to specific species.
25)	Clever et al. (2014) recommend the data from Battino (1981).
26)	Battino (1981) concludes that ozone aqueous chemistry needs further clarification. Data from Roth and Sullivan (1981) are recommended, in spite of limitations and assumptions of the data.
27)	Roth and Sullivan (1981) found that H_s depends on the concentration of OH⁻.
28)	Value at T = 291 K.
29)	Value given here as quoted by Durham et al. (1981).
30)	Lide and Frederikse (1995) present an unusually low value for the Henry solubility of ozone. They refer to Battino (1981) as the source, but the quoted value cannot be found there.

The numbers of the notes are the same as in Sander (2023). References cited in the notes can be found here.

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